饮料及配制酒中11种有机合成色素的低共熔溶剂萃取/高效液相色谱法测定

周佳; 禹洁; 朱书强; 邵永华; 黄韡; 祖新

doi:doi：10.3969/j.issn.1004-4957.2019.11.012

您当前的位置：

首页 >

文章列表页 >

饮料及配制酒中11种有机合成色素的低共熔溶剂萃取/高效液相色谱法测定

- 饮料及配制酒中11种有机合成色素的低共熔溶剂萃取/高效液相色谱法测定
- Determination of 11 Organic Synthetic Pigments in Drink and Compound Wine by Deep Eutectic Solvent Extraction/High Performance Liquid Chromatography
- 分析测试学报 2019年38卷第11期页码：1358-1363
- 作者机构：
  
  甘肃省食品检验研究院
- 作者简介：
- 基金信息：
  
  甘肃省科技计划重点研发项目(18YF1FA048);甘肃省食品药品科研计划项目(2018GSFDA040)
- DOI：doi：10.3969/j.issn.1004-4957.2019.11.012
  中图分类号：
- 纸质出版：2019
- 稿件说明：
移动端阅览
周佳, 禹洁, 朱书强, 邵永华, 黄韡, 祖新. 饮料及配制酒中11种有机合成色素的低共熔溶剂萃取/高效液相色谱法测定[J]. 分析测试学报, 2019,38(11):1358-1363.

周佳, 禹洁, 朱书强, 邵永华, 黄韡, 祖新. Determination of 11 Organic Synthetic Pigments in Drink and Compound Wine by Deep Eutectic Solvent Extraction/High Performance Liquid Chromatography[J]. 2019, 38(11): 1358-1363.
周佳, 禹洁, 朱书强, 邵永华, 黄韡, 祖新. 饮料及配制酒中11种有机合成色素的低共熔溶剂萃取/高效液相色谱法测定[J]. 分析测试学报, 2019,38(11):1358-1363. DOI： doi：10.3969/j.issn.1004-4957.2019.11.012.

周佳, 禹洁, 朱书强, 邵永华, 黄韡, 祖新. Determination of 11 Organic Synthetic Pigments in Drink and Compound Wine by Deep Eutectic Solvent Extraction/High Performance Liquid Chromatography[J]. 2019, 38(11): 1358-1363. DOI： doi：10.3969/j.issn.1004-4957.2019.11.012.

摘要

采用四丁基氯化铵和辛酸合成新型疏水性低共熔材料，并以其为萃取剂建立了快速测定饮料、配制酒中11种有机合成色素的高效液相色谱方法。样品经水稀释，以200 μL低共熔溶剂萃取后，采用高效液相色谱-二极管阵列检测器(HPLC-DAD)检测，外标法定量。结果表明，11种有机合成色素在各自的质量浓度范围内均呈良好的线性关系，相关系数(r2)均大于0996，检出限为0.03~0.31 mg/kg，定量下限为0.08~1.02 mg/kg；加标回收率为92.6%~103%，相对标准偏差(RSD)为0.98%~4.3%。该方法快速、简便、精准，适用于饮料、配制酒中有机合成色素的检测。

Abstract

A method of high performance liquid chromatography(HPLC) with deep eutectic solvent extraction was established for the rapid determination of organic synthetic pigments in drinks and compound wines.The deep eutectic solvent was a new hydrophobic eutectic material synthesized with tetrabutyl ammonium chloride and octanoic acid.Samples were dissolved with water

then extracted with 200 μL deep eutectic solvent

finally detected by HPLC-diode array detector(DAD) and quantified by external standard method.Results indicated that there were good linear relationships for 11 kinds of organic synthetic pigments in respective mass concentration ranges with their correlation coefficients(r2) all greater than 0.996.The limits of detection(LOD)and the limits of quantitation(LOQ) were in the ranges of 0.03-0.31 mg/kg and 0.08-1.02 mg/kg

respectively.The recoveries ranged from 92.6% to 103% with relative standard deviations(RSD)of 0.98%-4.3%.The method is rapid

simple and accurate

and is suitable for the determination of organic synthetic pigments in drinks and compound wines.

关键词

Keywords

references

浏览量

303

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

煅牡蛎标准汤剂“量-质”传递规律研究

超声波辅助萃取/HPLC-ELSD分析烟用香原料中水溶性糖

喹啉羧酸共价有机框架微球在线固相萃取4种黄曲霉毒素

强化微塑料生物降解的基因工程菌构建策略与作用机制研究进展

水环境pH驱动微塑料老化的机制、效应与分析表征技术瓶颈