1.天津中医药大学 组分中药国家重点实验室,天津 301617
2.南开大学 化学学院,分析科学研究中心, 天津 300071
杨成雄,博士,副教授,研究方向:色谱分析,E-mail:cxyang@nankai.edu.cn
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李雪,杨成雄.基于共价-有机骨架固定相的色谱分离应用研究进展[J].分析测试学报,2021,40(07):1091-1097.
LI Xue,YANG Cheng-xiong.Progress on Application of Covalent-Organic Frameworks-based Stationary Phases in Chromatography[J].Journal of Instrumental Analysis,2021,40(07):1091-1097.
李雪,杨成雄.基于共价-有机骨架固定相的色谱分离应用研究进展[J].分析测试学报,2021,40(07):1091-1097. DOI: 10.3969/j.issn.1004-4957.2021.07.018.
LI Xue,YANG Cheng-xiong.Progress on Application of Covalent-Organic Frameworks-based Stationary Phases in Chromatography[J].Journal of Instrumental Analysis,2021,40(07):1091-1097. DOI: 10.3969/j.issn.1004-4957.2021.07.018.
共价-有机骨架材料(COFs)是一类由轻质元素通过共价键形成的多孔材料,具有比表面积大、稳定性好、孔径可调、功能多样、结构可修饰等特点,在分析化学领域如样品前处理和色谱分离等方面显示出了良好的应用前景。其中COFs作为新颖色谱固定相在高效液相色谱、气相色谱和毛细管电色谱分离应用研究也逐渐引起了人们的关注。色谱分离所用COFs均具有良好的化学稳定性,但比表面积、孔径和性质各异,适用于分离不同类型的目标物如有机小分子、同分异构体和手性化合物等。该文综述了近年来以COFs为固定相的色谱分离应用研究进展,包括基于COFs的色谱固定相/色谱柱的制备及其色谱分离应用,并对其进行了展望。
Covalent organic frameworks (COFs)are a recent class of porous functional materials composed of diverse light elements (C, H, O, N and B)through various robust covalent bonds. Their unique properties such as large surface areas, excellent stabilities, tunable pores, diverse functions and designable structures make COFs quite promising in analytical chemistry such as sample pretreatment and chromatographic separation. COFs used as novel stationary phases in high performance liquid chromatography (HPLC), gas chromatography (GC)and capillary electrochromatography (CEC)have attracted great concerns recently. COFs with large surface area, good thermal and chemical stability are ideal candidates in GC. The good solvent stability and large surface area also make COFs potentially useful in HPLC and CEC. COFs used in chromatographic separation all possess good chemical stability, but have different specific surface area, topological structures, pore sizes, properties and selectivities, and are suitable for the resolution of different types of targets such as small organic molecules, position isomers and even chiral compounds. This review presents the recent progress on applications of COFs-based stationary phases and columns in chromatography. The preparation and applicability of these COFs-based stationary phases and columns in chromatographic separation are discussed. The application prospect of COFs in chromatographic separation is also presented.
共价-有机骨架固定相高效液相色谱(HPLC)气相色谱(GC)毛细管电色谱(CEC)
covalent-organic frameworkstationary phasehigh performance liquid chromatography(HPLC)gas chromatography(GC)capillary electrochromatography(CEC)
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