Simultaneous Determination of Six Kinds of Banned Organophosphorous Flame Retardants in Textiles by Gas Chromatography Tandem Mass Spectrometry Combined with Ultrasonic Extraction
Simultaneous Determination of Six Kinds of Banned Organophosphorous Flame Retardants in Textiles by Gas Chromatography Tandem Mass Spectrometry Combined with Ultrasonic Extraction[J]. 2011,30(8):917-921.
Simultaneous Determination of Six Kinds of Banned Organophosphorous Flame Retardants in Textiles by Gas Chromatography Tandem Mass Spectrometry Combined with Ultrasonic Extraction[J]. 2011,30(8):917-921.DOI:
An effective method was established for the simultaneous determination of six kinds of banned organophosphorous flame retardants,including tris(1-aziridinyl) phosphine oxide(TEPA),tris(2-chloroethyl)phosphate(TCEP),tris(2,3-dichloropropyl)phosphate(TDCP),bis(2,3-dibromopropyl) phosphate(DDBPP),tri-o-tolyl phosphate(TOCP) and tris(2,3-dibromopropyl)phosphate(TRIS),in textiles by gas chromatography tandem mass spectrometry(GC-MS/MS) combined with ultrasonic extraction.The organophosphorous flame retardants in textiles were first ultrasonically extracted with acetone,and then analyzed by GC-MS/MS under multiple reaction monitoring (MRM) mode.The linear ranges of TEPA,TCEP,TDCP,DDBPP,TOCP and TRIS were 9.17-366.80,0.95-75.98,1.04-83.20,41.60-832.00,3.80-75.90,40.48-809.60 μg/L,respectively,and their quantitation limits(S/N=10)were 3.0,0.2,0.3,25.0,2.5,29.0 μg/kg,respectively.The spiked recoveries varied from 83% to 96% with RSDs of 3.7%-9.8%.The developed method was simple,rapid,sensitive and accurate,and could satisfy completely the demand of the analysis of banned organophosphorous flame retardants in textiles.
关键词
超声萃取气相色谱-串联质谱法(GC-MS/MS)纺织品有机磷阻燃剂
Keywords
ultrasonic extractiongas chromatography tandem mass spectrometry(GC-MS/MS)textilesorganophosphorous flame retardant