Due to the edges containing a large number of functional groups(such as carboxyl groups),graphene oxide sheet could be effectively used to form a nuclear site and used as a template for biomimetic synthesis.In this paper,the application of graphene oxide used as the template for biomimetic synthesis of organic/inorganic hybrid materials was reviewed.The fundamental principle was introduced，and the preparation methods of different types of hybrid materials were summarized.The new trends of graphene based organic/inorganic hybrid materials were discussed.