1. 环境保护部标准样品研究所
2. 国家环境保护污染物计量和标准样品研究重点实验室
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王帅斌, 杜健, 钱萌, 等. 臭氧标准参考光度计间接比对技术[J]. 分析测试学报, 2016,35(10):1355-1359.
An Indirect Comparison Technique of Ozone Standard Reference Photometer[J]. 2016,35(10):1355-1359.
参照国际计量局有关臭氧标准参考光度计(Standard Reference Photometer,SRP)间接比对的操作规程和美国环境保护署有关臭氧参考光度计之间比对验证的规定,采用臭氧传递标准,通过比对前的准备、比对过程的确定、比对结果的处理、比对指标的评价等步骤,开展了臭氧标准参考光度计间接比对实验。以SRPⅠ与SRPⅡ间接比对为例,SRPⅠ与SRPⅡ间接比对所得两个关系式的斜率分别为1.003 26和1.003 58,截距分别为0.109 05 nmol/mol和0.080 99 nmol/mol,结果显示两台SRP之间具有很好的一致性,比对结果符合美国环境保护署关于SRP之间比对的指标。建立了臭氧标准参考光度计之间的比对方法,适用于环境空气臭氧量值传递源头间的比对。
Consulting the indirect comparison protocol of Standard Reference Photometer(SRP) from BIPM(Bureau International des Poids et Mesures) and U.S.EPA(Environmental Protection Agency),the indirect comparison technique of SRPs was developed by preparation of pre-comparison,confirmation of comparison procedure,treatment of comparison results and evaluation of comparison index through the ozone transfer standard.Furthermore,SRPⅠand SRPⅡ were indirectly compared,while the slopes of the two indirect comparison equations between SRPⅠand SRPⅡ were 1.003 26 and 1.003 58 with the intercepts of 0.109 05 nmol/mol and 0.080 99 nmol/mol,respectively,which indicated that there was a good consistency between the two SRPs,and the indirect comparison results could meet the comparison index of SRPs by U.S.EPA.The indirect comparison method of SRPs was established,and it was suitable for the comparison between SRPs.
臭氧标准参考光度计间接比对技术
ozonestandard reference photometerindirect comparisontechnique
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