High Throughput Detection of 12 Herbicides in Environmental Water by UPLC－MS/MS Method with Solvent Induced Extraction

CHEN Jing; WANG Bo; WANG Xin-chao; WANG Juan; WANG Yu-xin; SHEN Yue; QU De-ye

doi:10.19969/j.fxcsxb.22071203

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High Throughput Detection of 12 Herbicides in Environmental Water by UPLC－MS/MS Method with Solvent Induced Extraction

Experimental Techniques and Methods | 更新时间：2023-05-25

- High Throughput Detection of 12 Herbicides in Environmental Water by UPLC－MS/MS Method with Solvent Induced Extraction
- Journal of Instrumental Analysis Vol. 42, Issue 1, Pages: 82-88(2023)
- 作者机构：
  
  1.西北师范大学地理与环境科学学院，甘肃兰州 730070
  2.甘肃省绿洲资源环境与可持续发展重点实验室，甘肃兰州 730070
  3.兰州海关技术中心，甘肃兰州 730070
- 作者简介：
- 基金信息：
- DOI：10.19969/j.fxcsxb.22071203
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陈静,王波,王新潮等.溶剂诱导萃取/UPLC－MS/MS法高通量检测环境水体中12种除草剂[J].分析测试学报,2023,42(01):82-88.

CHEN Jing,WANG Bo,WANG Xin-chao,et al.High Throughput Detection of 12 Herbicides in Environmental Water by UPLC－MS/MS Method with Solvent Induced Extraction[J].Journal of Instrumental Analysis,2023,42(01):82-88.
陈静,王波,王新潮等.溶剂诱导萃取/UPLC－MS/MS法高通量检测环境水体中12种除草剂[J].分析测试学报,2023,42(01):82-88. DOI： 10.19969/j.fxcsxb.22071203.

CHEN Jing,WANG Bo,WANG Xin-chao,et al.High Throughput Detection of 12 Herbicides in Environmental Water by UPLC－MS/MS Method with Solvent Induced Extraction[J].Journal of Instrumental Analysis,2023,42(01):82-88. DOI： 10.19969/j.fxcsxb.22071203.

摘要

以二氯甲烷为萃取剂，建立了测定环境水样中12种除草剂的溶剂诱导萃取/超高效液相色谱－串联质谱（UPLC－MS/MS）法。通过单因素实验确定提取剂乙腈的体积、萃取剂的种类和体积、离心时间，并结合响应面分析，得到最优的前处理方法；在仪器方法建立过程中对质谱参数、色谱柱、流动相进行了优化。在最优条件下，12种除草剂的线性关系良好，相关系数（,r,）均大于0.999 5，方法检出限为0.05 ~ 0.5 μg/L，定量下限为0.2 ~ 5.0 μg/L，平均回收率为83.0% ~ 110%，相对标准偏差为0.30% ~ 5.0%。该方法简便快捷、灵敏度高、有机溶剂用量少，适用于环境水体中除草剂的高通量检验。

Abstract

An ultra performance liquid chromatography－tandem mass spectrometry（UPLC－MS/MS） with dichloromethane solvent induced extraction was established for the determination of 12 herbicides in environmental water．The volume of extractant acetonitrile，the type and dosage of extractant，and the centrifugation time were determined by single factor test．Combined with response surface analysis，an optimal pretreatment method was obtained．Meanwhile，mass spectrum parameters，chromatographic column and different mobile phases were also optimized during the establishment of the instrument method．Under the optimal conditions，the calibration curves for 12 herbicides were in good linear relationships，with their correlation coefficients（,r,） greater than 0.999 5．The limits of detection and the limits of quantitation were in the ranges of 0.05－0.5 μg/L and 0.2－5.0 μg/L，respectively．Average recoveries ranged from 83.0% to 110%，with relative standard deviations of 0.30%－5.0%．The method is simple，sensitive and low organic solvent consumption，and it is suitable for the high throughput inspection of actual samples.

关键词

除草剂溶剂诱导萃取超高效液相色谱－串联质谱环境水体

Keywords

herbicidesolvent induced extractionultra performance liquid chromatography-tandem mass spectrometryenvironmental water

references

《Environmental Science Dictionary》 Editorial Board. Environmental Science Dictionary（Revised Edition）. Beijing：China Environmental Science Press（《环境科学大辞典》编委会.环境科学大辞典（修订版）．北京：中国环境科学出版社），2008.

Zhu F Q，Wu S D，Han Y J，Guo Y P，Tian H G，Han J Z．Environ. Sci. （朱富强，吴树栋，韩岩君，郭宇鹏，田洪根，韩家忠．环境化学），2020，39（3）：835－839.

Sun R H，Wang T，Wang X，Ji W H．J. Instrum. Anal. （孙日晗，王涛，王晓，纪文华．分析测试学报），2017，36（6）：750－755.

Zhu Q，Long B H，Chen X H，Yan X，Zhu H N，Feng J，Xu W L，Wang Z B．J. Instrum. Anal. 朱清，龙冰华，陈星航，闫徐，朱红年，冯吉，徐尉力，王志兵．分析测试学报），2021，40（10）：1467－1473.

Zhao G，Song S，Wang C．Anal. Chim. Acta，2011，708（1/2）：155－159.

Nagaraju D，Huang S D．J. Chromatogr. A，2007，1161（1/2）：89－97.

Zhu F Q，Wu S D，Han Y J，Guo Y P．J. Instrum. Anal. （朱富强，吴树栋，韩岩君，郭宇鹏．分析测试学报），2021，40（9）：1279－1285.

Xu H，Wang D X．Occup. Health（许韡，王丹侠．职业与健康），2017，33（14）：2004－2008.

Wang S L，Yang S P，Liu F M，Xue J Y，You X W．Chin. J. Pestic. Sci. （王素利，杨素萍，刘丰茂，薛佳莹，尤祥伟.农药学学报），2012，14（5）：461－474.

Fu R N．Chin. J. Anal. Lab. （傅若农．分析试验室），2015，34（5）：602－620.

Fang G，Wang X，Wang S．Chromatographia，2010，72（5/6）：403－409.

Bai X Y．Development and Application for Test Method of 82 Kinds of Pesticides in Groundwater. Beijing：China University of Geosciences（白雪媛．地下水中82种农药测试方法开发与应用．北京：中国地质大学），2017.

Zhang M S，Liu G Z，Li S J，Chen B，Yao S Z．Chem. J. Chin. Univ. （张鸣珊，刘国柱，李圣军，陈波，姚守拙．高等学校化学学报），2010，31（8）：1517－1521.

Wang Q．Determination of Organic Pollutants in Environmental Water by Ultrasonication Assisted Dispersive Liquid－Liquid Microextraction Coupled with HPLC. Lanzhou：Northwest Normal University（王青．超声辅助分散液－液微萃取/高效液相色谱联用测定环境水样中的有机污染物．兰州：西北师范大学），2013.

Chen X，Wang B，Ye R，Li M，Zhou J G，Zhang B，Han S Y．Food Sci. （陈霞，王波，叶融，李敏，周继亘，张波，韩舜愈．食品科学），2017，38（6）：215－220.

Zhu L，Zhang R，Zhang B，Ye J，Wang S X，Wang S S，Guo B Y，Zhang Z J，Liu X H．J. Chin. Cereals Oil Assoc. 朱琳，张蕊，张冰，叶金，王松雪，王松山，郭宝元，张志军，刘鑫辉．中国粮油学报），2021，36（5）：149－153.

Guan X T，Zhang Q Y，Huang J R，Wu Y L．Guangdong Chem. Ind. （关小桃，张琪雨，黄军如，吴艳龙．广东化工），2021，48（11）：144－146.

GB/T 5750.8－2006. Standard Examination Methods for Drinking Water－Organic Parameters. National Standards of the People’s Republic of China（生活饮用水标准检验方法有机物指标．中华人民共和国国家标准）.

GB/T 23214－2008. Determination of 450 Pesticides and Related Chemicals Residues in Dringking Water－LC－MS－MS Method. National Standards of the People’s Republic of China

饮用水中450种农药及相关化学品残留量的测定液相色谱－串联质谱法．中华人民共和国国家标准.

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