Simultaneous Determination of 64 Odor-causing Substances in Surface Water by Headspace Arrow Solid-phase Microextraction/Gas Chromatography-Triple Quadrupole Mass Spectrometry
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Simultaneous Determination of 64 Odor-causing Substances in Surface Water by Headspace Arrow Solid-phase Microextraction/Gas Chromatography-Triple Quadrupole Mass Spectrometry
Journal of Instrumental AnalysisVol. 45, Pages: 1-9(2026)
CHEN Xiu-wen,WANG Lei,KE Tian-ying,ZHAO Jun-ming,ZHOU Ming.Simultaneous Determination of 64 Odor-causing Substances in Surface Water by Headspace Arrow Solid-phase Microextraction/Gas Chromatography-Triple Quadrupole Mass Spectrometry[J].Journal of Instrumental Analysis,2026,45(05):1-9.
CHEN Xiu-wen,WANG Lei,KE Tian-ying,ZHAO Jun-ming,ZHOU Ming.Simultaneous Determination of 64 Odor-causing Substances in Surface Water by Headspace Arrow Solid-phase Microextraction/Gas Chromatography-Triple Quadrupole Mass Spectrometry[J].Journal of Instrumental Analysis,2026,45(05):1-9. DOI: 10.12452/j.fxcsxb.25091702.
Simultaneous Determination of 64 Odor-causing Substances in Surface Water by Headspace Arrow Solid-phase Microextraction/Gas Chromatography-Triple Quadrupole Mass Spectrometry
To address the odor issue in surface water,a method for the simultaneous determination of 64 odor-causing substances in surface water was established based on headspace arrow solid-phase microextraction coupled with gas chromatography-triple quadrupole mass spectrometry(HS-SPME Arrow/GC-MS/MS). The targeted odor-causing substances cover multiple categories,including typical algal-derived and industrial-derived ones such as sulfides/thiols,halohydrocarbons/aromatic hydrocarbons,terpenes,pyrazines,esters,phenols,aldehydes and ketones,ethers,and amines. Single-factor experiments were conducted to investigate the effects of parameters,including SPME fiber type,extraction time,extraction temperature,incubation time,and sodium chloride(NaCl) addition amount,on the extraction efficiency of the 64 odor-causing substances. The results indicated that the optimal conditions were as follows:after introducing 1.80 g NaCl to 5.0 mL solution,the bottle was incubated for 5 min at 60 ℃,then a DVB/CAR/PDMS(divinylbenzene/carboxen/ polydimethylsiloxane) SPME fiber was used for the ex
traction for 30 min.The limits of detection for the 64 odor-causing substances ranged from 0.92 to 29.06 ng/L,with all linear correlation coefficients(
r
2
) greater than 0.990 in the linear range of 5.0-2 000 ng/L. At three spiked concentration levels,the average spiked recoveries ranged from 60.1% to 134%,and the relative standard deviations(RSDs) varied between 1.8% and 21%. When this method was used to detect 5 surface water samples from Shanghai,methyl sulfide(5.13-18.04 ng/L),methanethiol(6.58-25.12 ng/L),and 2-methylisoborneol(2-MIB,11.13-11.42 ng/L) were detected,respectively.This method is characterized by automated sample pretreatment,and can be applied to the high-throughput rapid screening of odor-causing substances in surface water.
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Dai Q Z , Xu B , Xu F , Zhou X S , Wu J . Proceedings of 2023 China Water Resoure Academic Conference(Vol. 1)(代倩子,徐彬,徐枫,周鑫盛,吴娟 . 2023中国水利学术大会论文集(第一分册)) , 2023 : 273 - 278 .
Wu J , Lin H J . Proceedings of 14th Flood Control Drought Relief Informatization Forum(吴娟,林荷娟 . 第十四届防汛抗旱信息化论坛论文集) , 2024 : 568 - 576 .
Chen F , Tang F L , Xu J F , Wang Z M , Wang L , Zhang H J . Environ. Sci. (陈峰,唐访良,徐建芬,王浙明,王蕾,张杭君. 环境科学), 2018 , 39 ( 2 ): 648 - 654 .
Gan H H , Yu M F , Liu C Y , Zhou H D , Li Z G . J. Ningbo Univ .: Nat. Sci. Eng. Ed . (甘慧慧,俞梦飞,柳成荫,周海东,李祖光. 宁波大学学报:理工版), 2025 , 38 ( 1 ): 73 - 81 .
Wang C M , Yang J W , Chen Y , Li X Y , Qiu F G . J. Hazard. Mater. , 2022 , 430 : 128435 .
Zhou X S . Water Purif . Technol. (周鑫盛. 净水技术), 2024 , 43 ( S2 ): 276 - 283 .
Li F D , Wang X , Shi Y D , Wu S H , Chen J H , Lin H . J. Instrum. Anal. (李丰铎,王洵,石亚东,吴淑焕,陈军辉,林洪. 分析测试学报), 2024 , 43 ( 4 ): 582 - 589 .
GB/T 5750 . 8 -2023. Standard Examination Methods for Drinking Water—Part 8 :Organic Parameters. National Standards of the People's Republic of China(生活饮用水标准检验方法 第8部分:有机物指标 . 中华人民共和国国家标准) .
Hu Y B , Wu M L , Fan L Q , Fu J X , Wang S P . Water Purif . Technol. (胡颖斌 ,吴孟李,范利青,傅金祥,王少坡. 净水技术), 2025 , 44 ( S1 ): 436 - 441 .
Chen X W , Wang W Y , Wang L , Huang B T . Water Purif . Technol. (陈秀雯 ,王玮祎,王磊,黄波涛. 净水技术), 2022 , 41 ( S1 ): 338 - 342 .
Zhang Y X , Qiu F G , Wang C M , Zhou X S , Li M . Chin. J. Environ. Eng. (张永鑫,仇付国,王春苗,周鑫盛,李梅. 环境工程学报) , 2023 , 17 ( 11 ): 3730 - 3737 .
Liu Q , Zhang H , Ye Y Q , Lai F R , Wu H , Li X F . J. Instrum. Anal. (刘琪,张华,叶远青,赖富饶,吴晖,李晓凤. 分析测试学报), 2025 , 44 ( 1 ): 135 - 144 .
Li B . Water Purif. Technol. (李冰. 净水技术), 2023 , 42 ( 11 ): 191 - 199 .
Xu L Y , Hou Y , Yang Q , Cui C , Wang C Y . Chin . Dairy Ind. (许凌云,侯阳,杨倩,崔春,王储炎. 中国乳品工业), 2022 , 50 ( 7 ): 53 - 60 .
Xing K N , Yang R Q , Dong L P , Song G , Li J Y , Zhang Y F , Ren X X . Chin . J . Forensic Sci . 邢凯宁 , 杨瑞琴 , 董林沛 , 宋歌 , 李佳宜 , 张云峰 , 任昕昕 . 中国司法鉴定) , 2025 ,( 1 ): 28 - 36 .
Guo Q Y , Wang C M , Sun D L , Chen Z , Qiu F G . Chin . Water Wastewater (郭巧媛,王春苗,孙道林,陈卓,仇付国. 中国给水排水), 2022 , 38 ( 6 ): 132 - 138 .
Huang B T , Chen X W . Environ . Pollut. Control (黄波涛,陈秀雯. 环境污染与防治), 2023 , 45 ( 6 ): 837 - 842 .
Yin Y M , Luo J , Sun X Y , Yu W J , Wang X , Li B . Chem. Anal. Meterage (尹燕敏,骆骏,孙欣阳,余文杰,王欣,李冰. 化学分析计量), 2025 , 34 ( 4 ): 85 - 91 .
Wu Y J , Chen S , Deng Y , Wang H Y , Lin S B . Chin. Water Wastewater (吴颖娟,陈飒,邓怡,王红宇,林少彬. 中国给水排水), 2017 , 33 ( 24 ): 124 - 127 .
Liu J Z , Chen Q L , Wu Y J , He J , Wu S J , Lin Z G . J. Chin. Mass Spectrom. Soc. (刘建卓,陈秋玲,吴岳峻,何佳,吴诗剑,林竹光. 质谱学报), 2023 , 44 ( 4 ): 576 - 588 .
Di X Y . Water Purif . Technol. (狄欣宜. 净水技术), 2024 , 43 ( 3 ): 194 - 203 .
Ma X J , Li M F , Cao F F . Chem. Anal. Meterage (马小杰,李明芳,曹方方. 化学分析计量), 2024 , 33 ( 6 ): 45 - 49 .
GB 5749 - 2022 . Standards for Drinking Water Quality. National Standards of the People's Republic of China(生活饮用水卫生标准. 中华人民共和国国家标准) .
GB 3838 - 2002 . Environmental Quality Standards For Surface Water. National Standards of the People's Republic of China(地表水环境质量标准. 中华人民共和国国家标准) .
Wang Y Z , Zhang C M , Zhu Y X , Gao B , Zheng B H . Proceedings of 2019 China Water Resoure Society Academic Annual Meeting(Vol. 4)(王愿珠,张春梅,朱宇轩,高博,郑丙辉 . 中国水利学会2019学术年会论文集第四分册) , 2019 : 334 - 342 .
Zhang Y X , Qiu F G , Wang C M , Zhou X S , Li M . Acta Sci . Circumstantiae (张永鑫,仇付国,王春苗,周鑫盛,李梅. 环境科学学报), 2023 , 43 ( 12 ): 65 - 75 .
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