Determination of Polychlorinated Terphenyl in Heavy Oil by Distillation Cleavage-Solid Phase Extraction-Ni Online Catalysis-Gas Chromatography-Tandem Mass Spectrometry
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Determination of Polychlorinated Terphenyl in Heavy Oil by Distillation Cleavage-Solid Phase Extraction-Ni Online Catalysis-Gas Chromatography-Tandem Mass Spectrometry
Journal of Instrumental AnalysisVol. 44, Pages: 1-8(2025)
ZHANG Zi-hao,LIN Hai,XU Jin-long,TAN Zhi-yi,XIAO Qian,TANG Yuan-yuan,ZHENG Yu-xi.Determination of Polychlorinated Terphenyl in Heavy Oil by Distillation Cleavage-Solid Phase Extraction-Ni Online Catalysis-Gas Chromatography-Tandem Mass Spectrometry[J].Journal of Instrumental Analysis,2025,44(11):1-8.
ZHANG Zi-hao,LIN Hai,XU Jin-long,TAN Zhi-yi,XIAO Qian,TANG Yuan-yuan,ZHENG Yu-xi.Determination of Polychlorinated Terphenyl in Heavy Oil by Distillation Cleavage-Solid Phase Extraction-Ni Online Catalysis-Gas Chromatography-Tandem Mass Spectrometry[J].Journal of Instrumental Analysis,2025,44(11):1-8. DOI: 10.12452/j.fxcsxb.25020466.
Determination of Polychlorinated Terphenyl in Heavy Oil by Distillation Cleavage-Solid Phase Extraction-Ni Online Catalysis-Gas Chromatography-Tandem Mass Spectrometry
A method for determining the content of polychlorinated terphenyls in heavy oil samples based on distillation cutting separation-solid phase extraction-Ni online catalysis-gas chromatography-tandem mass spectrometry method has been established. Nickel catalyst was used for online catalysis to convert chlorinated triphenyl compounds into dicyclohexylbenzene. Gas chromatography-tandem mass spectrometry in multiple reaction monitoring mode with internal standard method was used for determination. This study conducted optimization analyses on the distillation cut temperature,selection of catalytic carriers,solid phase extraction conditions,and catalytic reaction parameters. The linear ranges of the recovered curve ranged from 1 to 50 μg/mL. The limits of quantification(LOQ) were 0.35-0.60 μg/mL,which was equivalent to having a LOQ at 4.7 μg/kg. The recoveries ranged from 87.3% to 112%,and the relative standard deviations(RSDs) were not more than 6.2%. The results showed that this method was accurate and reliable,and was suitable for the analysis and determination of chlorinated triphenyl compounds in imported diluted asphalt,residual fuel oil,and other heavy oil products.
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