Preparation of Bismuth/Honeycomb-like Carbon Nanofibers and Its Electrochemical Sensitive Detection of Hydrogen Peroxide

WANG Feng-yi; ZHENG Bao-zhan; DU Juan; YANG Xiao-feng; HOU Xue; HE Guang-yun; QIN Shu-di

doi:10.12452/j.fxcsxb.24051134

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Preparation of Bismuth/Honeycomb-like Carbon Nanofibers and Its Electrochemical Sensitive Detection of Hydrogen Peroxide

Experimental Techniques and Methods | 更新时间：2024-12-13

- Preparation of Bismuth/Honeycomb-like Carbon Nanofibers and Its Electrochemical Sensitive Detection of Hydrogen Peroxide
- Journal of Instrumental Analysis Vol. 43, Issue 12, Pages: 1937-1943(2024)
- 作者机构：
  
  1.四川省农业科学院农业质量标准与检测技术研究所，四川成都 610066
  2.四川大学化学学院，四川成都 610064
- 作者简介：
- 基金信息：
- DOI：10.12452/j.fxcsxb.24051134
  CLC： O657.1
- Published：15 December 2024，
  
  Received：11 May 2024，
  
  Revised：16 June 2024，
- 稿件说明：
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王凤怡,郑保战,杜娟,杨晓凤,侯雪,贺光云,覃蜀迪.铋/蜂窝状碳纳米纤维的制备及其对过氧化氢的电化学高灵敏检测[J].分析测试学报,2024,43(12):1937-1943.

WANG Feng-yi,ZHENG Bao-zhan,DU Juan,YANG Xiao-feng,HOU Xue,HE Guang-yun,QIN Shu-di.Preparation of Bismuth/Honeycomb-like Carbon Nanofibers and Its Electrochemical Sensitive Detection of Hydrogen Peroxide[J].Journal of Instrumental Analysis,2024,43(12):1937-1943.
王凤怡,郑保战,杜娟,杨晓凤,侯雪,贺光云,覃蜀迪.铋/蜂窝状碳纳米纤维的制备及其对过氧化氢的电化学高灵敏检测[J].分析测试学报,2024,43(12):1937-1943. DOI： 10.12452/j.fxcsxb.24051134.

WANG Feng-yi,ZHENG Bao-zhan,DU Juan,YANG Xiao-feng,HOU Xue,HE Guang-yun,QIN Shu-di.Preparation of Bismuth/Honeycomb-like Carbon Nanofibers and Its Electrochemical Sensitive Detection of Hydrogen Peroxide[J].Journal of Instrumental Analysis,2024,43(12):1937-1943. DOI： 10.12452/j.fxcsxb.24051134.

摘要

利用静电纺丝技术制备具有连续大孔结构的蜂窝状碳纳米纤维（HCNFs），通过水热法将铋纳米颗粒（Bi NPs）修饰在HCNFs，构建无酶电化学传感器（Bi/HCNFs）用于过氧化氢（H

）电化学检测。通过扫描电子显微镜（SEM）和透射电子显微镜（TEM）对材料形貌进行表征，采用循环伏安法（CV）研究Bi/HCNFs修饰材料对H

的电催化行为，并对缓冲溶液的pH值以及工作电位等进行优化。在最佳条件下，通过计时电流法（

I~t

）测定传感器对H

的电催化性能，其在0.1~100 μmol·L

-1

浓度范围内表现出优异的电化学性能，检出限低至42 nmol·L

-1

，灵敏度为1 099.6 μA·L·mmol

-1

·cm

-2

；实际水样中H

的回收率为97.2%~102%。该传感器对H

检测表现出优异的重现性、稳定性以及实用性，具有良好的应用前景。

Abstract

Honeycomb-like carbon nanofibers（HCNFs） with continuous macroporous structure have been successfully prepared through electrospun technology. After that，Bi NPs were uniformly loaded on HCNFs forming composite（Bi/HCNFs） prepared by hydrothermal process，constructing an enzyme-free electrochemical sensor（Bi/HCNFs） for the electrochemical detection of hydrogen peroxide（H

）. The morphology of the materials was characterized by scanning electron microscopy（SEM） and transmission electron microscopy（TEM）. Furthermore，cyclic voltammetry（CV） was used to investigate the electrocatalytic behavior of Bi/HCNFs modified materials on H

，and pH of the buffer solution and working potential were optimized. The electrocatalytic performance of the sensor on H

was measured by chronoamperometry method（

I-t

） under the optimal conditions. In the concentration range of 0.1-100 μmol·L

-1

，the sensor exhibited excellent electrochemical performance，the detection limit was as low as 42 nmol·L

-1

，and the sensitivity was 1 099.6 μA·L·mmol

-1

·cm

-2

. It also shows excellent reproducibility，stability and practicability in response to H

，and the recoveries of practical water samples was 97.2%-102%，which has a good application prospect.

关键词

蜂窝状碳纳米纤维铋纳米颗粒电化学传感器过氧化氢

Keywords

honeycomb-like carbon nanofibersbismuth nanoparticleselectrochemical sensorhydrogen peroxide

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