Determination of 4，4'-Dichlorophenyl Sulfone Migration from Plastic Food Contact Material Products by Surface Enhanced Raman Spectroscopy

HU Jun-peng; XI Xiao-xiang; DAI Hang; LIU Cheng-hao; CHEN Rong-qiao; LIANG Ming; XIAN Yan-ping; WU Yu-luan; HOU Xiang-chang; ZHANG Hao-he

doi:10.12452/j.fxcsxb.24011101

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Determination of 4，4'-Dichlorophenyl Sulfone Migration from Plastic Food Contact Material Products by Surface Enhanced Raman Spectroscopy

Experimental Techniques and Methods | 更新时间：2024-07-08

- Determination of 4，4'-Dichlorophenyl Sulfone Migration from Plastic Food Contact Material Products by Surface Enhanced Raman Spectroscopy
- Journal of Instrumental Analysis Vol. 43, Issue 7, Pages: 1025-1031(2024)
- 作者机构：
  
  广州质量监督检测研究院，广州市食品安全风险动态监测与预警研究中心，广州市食品安全检测技术重点实验室，广州市NQI-质量安全科技协同创新中心，广东广州 511447
- 作者简介：
- 基金信息：
- DOI：10.12452/j.fxcsxb.24011101
  CLC： O657.3;TQ328.4
- Published：15 July 2024，
  
  Received：11 January 2024，
  
  Revised：03 March 2024，
- 稿件说明：
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胡均鹏,奚晓翔,戴航,刘城昊,陈荣桥,梁明,冼燕萍,吴玉銮,侯向昶,张浩和.表面增强拉曼光谱法测定食品接触用塑料材料及制品中4，4'-二氯二苯砜的迁移量[J].分析测试学报,2024,43(07):1025-1031.

HU Jun-peng,XI Xiao-xiang,DAI Hang,LIU Cheng-hao,CHEN Rong-qiao,LIANG Ming,XIAN Yan-ping,WU Yu-luan,HOU Xiang-chang,ZHANG Hao-he.Determination of 4，4'-Dichlorophenyl Sulfone Migration from Plastic Food Contact Material Products by Surface Enhanced Raman Spectroscopy[J].Journal of Instrumental Analysis,2024,43(07):1025-1031.
胡均鹏,奚晓翔,戴航,刘城昊,陈荣桥,梁明,冼燕萍,吴玉銮,侯向昶,张浩和.表面增强拉曼光谱法测定食品接触用塑料材料及制品中4，4'-二氯二苯砜的迁移量[J].分析测试学报,2024,43(07):1025-1031. DOI： 10.12452/j.fxcsxb.24011101.

HU Jun-peng,XI Xiao-xiang,DAI Hang,LIU Cheng-hao,CHEN Rong-qiao,LIANG Ming,XIAN Yan-ping,WU Yu-luan,HOU Xiang-chang,ZHANG Hao-he.Determination of 4，4'-Dichlorophenyl Sulfone Migration from Plastic Food Contact Material Products by Surface Enhanced Raman Spectroscopy[J].Journal of Instrumental Analysis,2024,43(07):1025-1031. DOI： 10.12452/j.fxcsxb.24011101.

摘要

建立了食品接触用塑料材料及制品中4，4'-二氯二苯砜迁移量的表面增强拉曼光谱测定方法。首先对制备的金纳米颗粒（AuNPs）进行表征，并通过理论计算对4，4'-二氯二苯砜的拉曼特征峰进行归属。随后参照GB 31604.1-2015和GB 5009.156-2016的规定进行食品接触用塑料材料及制品中4，4'-二氯二苯砜的迁移实验，将迁移液与AuNPs混合后进行SERS测试，并采用高效液相色谱法进行验证。4，4'-二氯二苯砜的特征峰（748 cm

-1

）强度与4，4'-二氯二苯砜质量浓度在0.05~10 mg/L范围内呈现良好的线性关系，相关系数为0.992 8，回收率为85.2%~93.4%，相对标准偏差为4.2%~6.6%，与HPLC方法结果基本一致。使用所建方法对5个不同品牌聚苯砜奶瓶中的4，4'-二氯二苯砜迁移量进行测定，结果均未检出。该方法具有快速、准确、操作简单等优点，可为食品接触用塑料材料及制品中4，4'-二氯二苯砜的检测提供技术参考。

Abstract

Surface enhanced Raman spectroscopy（SERS） was used to detect the migration of 4，4'-dichlorophenyl sulfone from plastic food contact materials. Au nanoparticles were prepared for SERS substrate and characterized，then the Raman characteristic peaks of 4，4'-dichlorophenyl sulfone were assigned by theoretical calculation. The migration behavior of 4，4'-dichlorophenyl sulfone in plastic food contact material products was carried out according to the GB 31604.1-2015 and GB 5009.156-2016. The obtained solution was passed through a 0.22 μm filter membrane，and mixed with AuNPs to perform SERS test，and the results were validated by high performance liquid chromatography（HPLC）. The intensity of the characteristic peak（748 cm

-1

） of 4，4'-dichlorophenyl sulfone showed a good linear relationship with the mass concentration of 4，4'-dichlorophenyl sulfone in the range of 0.05-10 mg/L，and the correlation coefficient was 0.992 8，the recoveries of SERS method were 85.2%-93.4% with the relative deviations of 4.2%-6.6%，meanwhile，these results were in good agreement with the HPLC. The proposed method was applied to the determination of 4，4'-dichlorophenyl sulfone in 5 brands of polyphenylene sulfone（PPSU） milk bottles.

This method is rapid，accurate and user friendly，and provides a technical reference for the determination of 4，4'-dichlorophenyl sulfone in food contact materials and products.

关键词

表面增强拉曼光谱4，4'-二氯二苯砜金纳米颗粒食品接触用塑料材料及制品迁移量

Keywords

surface enhanced Raman spectroscopy4，4'-dichlorophenyl sulfoneAu nanoparticlesplastic food contact material productsmigration

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