安徽工业大学 化学与化学工程学院,安徽 马鞍山 243032
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高越,侯金金,张建等.乙二胺杂化锗酸锌纳米带的绿色合成及其对铀酰离子的吸附与检测[J].分析测试学报,2023,42(05):577-585.
GAO Yue,HOU Jin-jin,ZHANG Jian,et al.Green Synthesis of an Ethylenediamine Hybrid Zinc Germanate Nanoribbon and Its Application in Adsorption and Detection of Uranyl Ions[J].Journal of Instrumental Analysis,2023,42(05):577-585.
高越,侯金金,张建等.乙二胺杂化锗酸锌纳米带的绿色合成及其对铀酰离子的吸附与检测[J].分析测试学报,2023,42(05):577-585. DOI: 10.19969/j.fxcsxb.23011503.
GAO Yue,HOU Jin-jin,ZHANG Jian,et al.Green Synthesis of an Ethylenediamine Hybrid Zinc Germanate Nanoribbon and Its Application in Adsorption and Detection of Uranyl Ions[J].Journal of Instrumental Analysis,2023,42(05):577-585. DOI: 10.19969/j.fxcsxb.23011503.
该文采用水热法合成了一种新型乙二胺杂化的锗酸锌纳米带(NH,2,-Zn,2,GeO,4, NRs),并用于铀酰离子(UO,,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=43462770&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=43462763&type=,1.86266661,3.72533321,)的检测和吸附。利用透射电子显微镜(TEM)、傅里叶变换红外光谱(FTIR)、X射线光电子能谱(XPS)、X射线衍射(XRD)、紫外-可见吸收光谱(UV-Vis)以及荧光光谱等对纳米带的结构及其光学特性进行了表征。结果表明NH,2,-Zn,2,GeO,4, NRs表面含有大量的—Ge—O—H和—NH,2,基团,为UO,,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=43463111&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=43463110&type=,2.53999996,3.72533321,的检测和吸附提供了丰富的结合位点。此外NH,2,-Zn,2,GeO,4, NRs可高效、高选择性地吸附和检测UO,,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=43463111&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=43463110&type=,2.53999996,3.72533321,,其对UO,,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=43463111&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=43463110&type=,2.53999996,3.72533321,的吸附符合Langmuir等温模型,最大吸附量为190 mg/g。基于天线效应,UO,,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=43463111&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=43463110&type=,2.53999996,3.72533321,与NH,2,-Zn,2,GeO,4, NRs的相互作用可打开UO,,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=43463111&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=43463110&type=,2.53999996,3.72533321,的绿色荧光,据此建立了灵敏的UO,,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=43462803&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=43462797&type=,2.53999996,3.72533321,检测方法,线性范围为0 ~ 45 μmol/L,检出限达0.202 μmol/L。对实际样品的加标回收率为87.2% ~ 102%,相对标准偏差低于10%。制备的NH,2,-Zn,2,GeO,4, NRs在实现UO,,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=43463111&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=43463110&type=,2.53999996,3.72533321,检测的同时可对其进行吸附,在实际水样检测中具有广泛的应用价值。
A kind of novel ethylenediamine hybrid zinc germanate nanoribbons(NH,2,-Zn,2,GeO,4, NRs) for adsorption and detection of uranyl ions was synthesized by hydrothermal synthesis.The structure and optical properties of NH,2,-Zn,2,GeO,4, NRs were characterized by transmission electron microscopy(TEM),Fourier transform infrared spectroscopy(FTIR),X-ray photoelectron spectroscopy(XPS),X-ray diffraction(XRD),thermogravimetric analysis(TG),X-ray energy spectrometry(EDS),ultraviolet-visible absorption spectrum(UV-Vis) and fluorescence spectroscopy.The results showed that the NH,2,-Zn,2,GeO,4, NRs have a crisscross band structure with good crystallinity and good thermal stability.Meanwhile,the surface of NH,2,-Zn,2,GeO,4, NRs contains rich amino groups,greatly improving the dispersion of the nanoribbons and facilitating the coordination of UO,,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=43463121&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=43463135&type=,2.87866688,4.31799984, with the surface amino groups,and then adsorbing UO,,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=43463121&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=43463135&type=,2.87866688,4.31799984,.Furthermore,the interaction between the —Ge—O—H group on the surface of zinc germanate nanoribbons and UO,,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=43463121&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=43463135&type=,2.87866688,4.31799984,,based on the antenna effect,turns on green fluorescence to realize the fluorescence detection of UO,,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=43463121&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=43463135&type=,2.87866688,4.31799984,.Therefore,the NH,2,-Zn,2,GeO,4, NRs could selectively and efficiently adsorb UO,,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=43463121&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=43463135&type=,2.87866688,4.31799984,,and their adsorption of uranyl ions conforms to Langmuir isotherm model,with a maximum adsorption capacity of 190 mg/g.On the other hand,a sensitive detection method for UO,,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=43463121&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=43463135&type=,2.87866688,4.31799984, was established based on the interaction between UO,,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=43463121&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=43463135&type=,2.87866688,4.31799984, and NH,2,-Zn,2,GeO,4, NRs,which could turn on green fluorescence,with a linear range of 0-45 μmol/L and a detection limit as low as 0.202 μmol/L.Results showed that only UO,,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=43463121&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=43463135&type=,2.87866688,4.31799984, can make NH,2,-Zn,2,GeO,4, NRs solution produce green fluorescence,while other ions have no fluorescence enhancement effect,indicating that the nano material has high selectivity and strong anti-interference ability.The method was successfully applied to the concentration analysis of UO,,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=43463121&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=43463135&type=,2.87866688,4.31799984, in tap water,lake water,river water and sea water.The recoveries for the actual samples ranged from 87.2% to 102%,with the relative standard deviations less than 10%.Therefore,the prepared NH,2,-Zn,2,GeO,4, NRs could be used for the simultaneous adsorption and detection of UO,,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=43463121&type=,http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=43463135&type=,2.87866688,4.31799984,,which has a wide application value in detection of actual water samples.
纳米带水热合成荧光检测铀酰离子吸附
nanoribbonhydrothermal synthesisfluorescence detectionuranyl ionsadsorption
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