Preparation of Fe@Fe<sub>3</sub>C－C and Its Efficient Adsorption of Bisphenol A

SHI Xiao-na; LIN Jia-wei; YIN Yi; ZHENG Guang-ming; JIN Hui; LIU Xue-wen; ZHAO Cheng; SHAN Qi

doi:10.19969/j.fxcsxb.23010802

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Preparation of Fe@Fe₃C－C and Its Efficient Adsorption of Bisphenol A

Scientific Papers | 更新时间：2023-06-15

- Preparation of Fe@Fe₃C－C and Its Efficient Adsorption of Bisphenol A
- Journal of Instrumental Analysis Vol. 42, Issue 6, Pages: 666-673(2023)
- 作者机构：
  
  1.上海海洋大学食品学院，上海 201306
  2.中国水产科学研究院珠江水产研究所，广东广州 510380
  3.农业农村部外来入侵水生生物防控重点实验室，广东广州 510380
  4.广东省水产动物免疫技术重点实验室，广东广州 510380
- 作者简介：
- 基金信息：
- DOI：10.19969/j.fxcsxb.23010802
  CLC：
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史晓娜,林嘉薇,尹怡等.Fe@Fe₃C－C的制备及对双酚A的高效吸附[J].分析测试学报,2023,42(06):666-673.

SHI Xiao-na,LIN Jia-wei,YIN Yi,et al.Preparation of Fe@Fe₃C－C and Its Efficient Adsorption of Bisphenol A[J].Journal of Instrumental Analysis,2023,42(06):666-673.
史晓娜,林嘉薇,尹怡等.Fe@Fe₃C－C的制备及对双酚A的高效吸附[J].分析测试学报,2023,42(06):666-673. DOI： 10.19969/j.fxcsxb.23010802.

SHI Xiao-na,LIN Jia-wei,YIN Yi,et al.Preparation of Fe@Fe₃C－C and Its Efficient Adsorption of Bisphenol A[J].Journal of Instrumental Analysis,2023,42(06):666-673. DOI： 10.19969/j.fxcsxb.23010802.

摘要

该研究制备了铁基金属有机骨架MIL－88B（Fe）衍生磁性多孔碳材料Fe@Fe,3,C－C，并将其用于水中双酚A（BPA）的高效吸附。采用X射线衍射、扫描电镜和比表面积及孔径分析等手段对材料的晶体结构、形貌和比表面积进行表征。结果表明，在高温作用下，MIL－88B（Fe）转化成Fe、Fe,3,C共掺杂碳材料（Fe@Fe,3,C－C）。Fe@Fe,3,C－C呈具有层次的炸裂状薄片结构且表面较为粗糙，比表面积为280.48 m,2,/g，与MIL－88B（Fe）相比增加了17倍。吸附实验表明，与MIL－88B（Fe）相比，高温煅烧（≥ 600 ℃）可以明显提升吸附性能。0.5 g/L的Fe@Fe,3,C－C在10 min内对10 mg/L的BPA去除率高达95%。材料具有较广的pH值适用范围（pH 2.0 ~ 10.0）和较强的抗无机盐离子（100 mmol/L）干扰能力，并能够用于高盐环境下的BPA吸附。拟二级动力学模型符合BPA在Fe@Fe,3,C－C上的吸附动力学曲线，吸附过程符合Langmuir模型。循环实验表明，Fe@Fe,3,C－C易于从水体中回收，且具有良好的可再生性能。上述研究结果表明Fe@Fe,3,C－C对水中BPA的去除具有较大的潜力。通过X射线光电子能谱、Zeta电位等表征探究吸附机理，结果显示Fe@Fe,3,C－C的主要作用机制为微孔填充、静电作用及π－π作用。

Abstract

A magnetic porous carbon material Fe@Fe,3,C－C was prepared by derivatizing an iron-based metal organic framework MIL－88B（Fe） in this paper，and applied to the efficient adsorption of bisphenol A（BPA） in water．The crystal structure，morphology and surface area of the material were characterized by X-ray diffraction，scanning electron microscopy，surface area and pore size analysis. The results showed that MIL－88B（Fe） was transformed into Fe and Fe,3,C co-doped carbon material（Fe@Fe,3,C－C） under high temperature，which had a layered burst-like sheet structure with rough surface．The specific surface area of Fe@Fe,3,C－C was 280.48 m,2,/g，17 times higher than that of MIL－88B（Fe）．The adsorption experiment showed that，compared with MIL－88B（Fe），calcination at high temperature（≥ 600 ℃） could improve the adsorption performance significantly．The removal rate of BPA of 10 mg/L reached 95% within 10 min when the amount of Fe@Fe,3,C－C was 0.5 g/L．The material had a wide range of pH application（pH 2.0－10.0） and a strong ability against ionic interference（100 mmol/L），and was suitable for BPA adsorption in high-salt environment．The pseudo-second-order kinetic model accords with the adsorption kinetics curve for BPA on Fe@Fe,3,C－C，and the adsorption process accords with the Langmuir model．Cyclic experiments showed that Fe@Fe,3,C－C has a good recycling ability and could be easily recovered from water．X-ray photoelectron spectroscopy and zeta potential were used to investigate the adsorption mechanism．The main mechanisms of Fe@Fe,3,C－C were π－π interaction，charge interaction and micropore filling．These results indicated that Fe@Fe,3,C－C has a great application potential in the removal of BPA in water.

关键词

MIL－88B（Fe）碳衍生化双酚A吸附

Keywords

MIL－88B（Fe）carbon derivatizationBPAadsorption

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Preparation of Fe@Fe3C－C and Its Efficient Adsorption of Bisphenol A

DOI：10.19969/j.fxcsxb.23010802

摘要

Abstract

关键词

Keywords

references

Preparation of Fe@Fe₃C－C and Its Efficient Adsorption of Bisphenol A