Detection of 4-Iodophenoxyacetic Acid Using a Graphene-loaded Tin Dioxide Electrochemical Sensor

WANG De-xiang; DUAN Yu; KONG Da-bin; WANG Hong; HU Min-kang; ZHANG Jin-ming; LI Sheng-nan; YANG Wen; DU Hai-jun

doi:10.19969/j.fxcsxb.22122502

您当前的位置：

首页 >

文章列表页 >

Detection of 4-Iodophenoxyacetic Acid Using a Graphene-loaded Tin Dioxide Electrochemical Sensor

Scientific Papers | 更新时间：2023-06-15

- Detection of 4-Iodophenoxyacetic Acid Using a Graphene-loaded Tin Dioxide Electrochemical Sensor
- Journal of Instrumental Analysis Vol. 42, Issue 6, Pages: 729-735(2023)
- 作者机构：
  
  1.贵州民族大学化学工程学院，贵州贵阳 550025
  2.贵州省农业科学院茶叶研究所，贵州贵阳 550006
  3.喀什大学新疆特色药食用植物资源化学实验室，新疆喀什 844006
- 作者简介：
- 基金信息：
- DOI：10.19969/j.fxcsxb.22122502
  CLC：
扫描看全文
王德响,段禹,孔大彬等.石墨烯负载二氧化锡电化学传感器检测4-碘苯氧乙酸研究[J].分析测试学报,2023,42(06):729-735.

WANG De-xiang,DUAN Yu,KONG Da-bin,et al.Detection of 4-Iodophenoxyacetic Acid Using a Graphene-loaded Tin Dioxide Electrochemical Sensor[J].Journal of Instrumental Analysis,2023,42(06):729-735.
王德响,段禹,孔大彬等.石墨烯负载二氧化锡电化学传感器检测4-碘苯氧乙酸研究[J].分析测试学报,2023,42(06):729-735. DOI： 10.19969/j.fxcsxb.22122502.

WANG De-xiang,DUAN Yu,KONG Da-bin,et al.Detection of 4-Iodophenoxyacetic Acid Using a Graphene-loaded Tin Dioxide Electrochemical Sensor[J].Journal of Instrumental Analysis,2023,42(06):729-735. DOI： 10.19969/j.fxcsxb.22122502.

摘要

该文通过水热法合成了珊瑚状的二氧化锡纳米颗粒，将其均匀生长在石墨烯上，构建了石墨烯负载二氧化锡电化学传感器对外源植物激素4-碘苯氧乙酸（4-IPOAA）进行电化学检测的方法。采用方波伏安法对不同浓度的4-IPOAA进行检测，结果显示4-IPOAA在0.5 ~ 20 µmol/L和20 ~ 100 µmol/L范围内具有良好线性关系，检出限（LOD，,S,/,N, = 3）为9.86 × 10,-2, µmol/L。4-IPOAA的电化学氧化过程受混合控制，有2个电子参与。所制备的传感器具有良好的重现性，相对标准偏差（RSD）不大于3.8%。使用加标回收法对白菜和黄瓜中的4-IPOAA进行检测，回收率分别为91.3% ~ 106%和91.4% ~ 116%，RSD分别为1.1% ~ 5.2%和3.8% ~ 8.0%。表明该传感器对4-IPOAA的实际检测具有良好的应用前景。

Abstract

A graphene-loaded tin dioxide electrochemical sensor for the electrochemical detection of exogenous plant hormone 4-iodophenoxyacetic acid（4-IPOAA） was fabricated in this paper．The graphene-loaded tin dioxide was constructed by synthesizing coral-like tin dioxide nanoparticles using hydrothermal method and homogeneously immobilizing them on graphene．The results showed that there was a good linearity for 4-IPOAA in the range of 0.5－20 µmol/L and 20－100 µmol/L by square wave voltammetry，and the limit of detection（LOD，,S,/,N ,= 3） was 9.86 × 10,-2, µmol/L．The electrochemical oxidation process of 4-IPOAA was controlled by mixing with the participation of 2 electrons．The prepared sensors showed good reproducibility with relative standard deviations（RSDs） not more than 3.8%．The spiked recoveries were in the range of 91.3%－106% and 91.4%－116% for 4-IPOAA in cabbage and cucumber，with RSDs of 1.1%－5.2% and 3.8%－8.0%，respectively，which indicated that the the sensor has a promising application prospect in the practical analysis of 4-IPOAA.

关键词

植物激素4-碘苯氧乙酸（4-IPOAA）石墨烯二氧化锡电化学检测

Keywords

plant hormones4-iodophenoxyacetic acid（4-IPOAA）graphenetin dioxideelectrochemical detection

references

Wang X Y．Encyclop. Knowl. （王小莜．百科知识），2015，（19）：11－14.

Tan T，Li Z，Mao X J，Wan Y Q，Qiu H D．Anal. Methods，2016，8（17）：3511－3516.

Wang M W．Determination Technology of Trace Plant Hormones and Carcinoid Markers Based on Functional Hydrophilic Resin. Baoding：Hebei University（王明伟．基于功能化亲水树脂的痕量植物激素及类癌标志物检测技术研究. 保定：河北大学），2021.

Chen H，Guo X F，Zhang H S，Wang H．J. Chromatogr. B，2011，879（20）：1802－1808.

Jiang C L，Dai J X，Han H L，Wang C，Zhu L，Lu C Y，Chen H B．J. Chromatogr. B，2020，1149：122144.

Takenaka S．J. Agric. Food Chem.，2002，50：7515－7519.

Du H J，Zhang Y，Wang X，Hu H L，Ai J X，Zhou H X，Yan X，Yang Y，Lu Z W．Biosensors（Basel），2022，12（9）：760.

Rao H B，Lu Z W，Ge H W，Liu X，Chen B Y，Zou P，Wang X X，He H，Zeng X Y，Wang Y Y．Mikrochim. Acta，2016，184（1）：261－269.

Ai J X，Du H J，Hu H L，Zhang Y，Li Y M，Luo L，Wu D．J. Instrum. Anal. 艾纪星，杜海军，胡华丽，张艳，李玉美，罗乐，伍丹．分析测试学报），2022，41（5）：797－804.

Zhang P G，Zeng W，Chen L．J. J. Mater. Sci.－Mater. Electron.，2015，27（2）：1201－1208.

Li Q．One-step Synthesis of Noble Metal-tin Dioxide Heterogeneous Materials and Their Application in the Preparation of Optoelectronic Sensors. Shanghai：Shanghai Normal University（李琪．贵金属－二氧化锡异质材料的一步法合成及其在光电传感器制备中的应用. 上海：上海师范大学），2022.

Sun J B，Luan Y B，Ma S H，Zheng Z，Xing Y W，Zhang H J．J. Instrum. Anal. （孙静波，栾业波，马世花，郑钊，邢仪雯，张洪静．分析测试学报），2022，41（11）：1664－1670.

Wang Z T，Jia D Z，Yin J Y，Li Y，Yan S X．J. Heilongjiang Univ. Sci. Technol. （王振廷，贾道增，尹吉勇，李洋，闫仕新．黑龙江科技大学学报），2022，32（3）：355－359.

Lu Z W，Wu L，Zhang J J，Dai W L，Mo G Q，Ye J S．Mater. Sci. Eng. C，2019，102：708－717.

Lu Z W，Dai W L，Lin X N，Liu B C，Zhang J J，Ye J P，Ye J S．Electrochim. Acta，2018，266：94－102.

Wang L，Yang X Y，Liu K，Chen M X，Xu X H．J. Instrum. Anal. （王玲，杨心悦，刘珂，陈明晰，徐新花．分析测试学报），2020，39（8）：1012－1017.

Ye X A，Zhang J L，Guan T T，Shi Y W．J. Instrum. Anal. （叶小爱，章家立，关婷婷，史怡炜．分析测试学报），2018，37（1）：39－44.

Wang Q，Li C，Zhang Z X．J. Instrum. Anal. （王琪，李超，张召香．分析测试学报），2021，40（8）：1197－1202.

Yang Y T，Wang Y，Zhou Y T，Chen Y J，Liang L，Li H M，Liu K P．China Meas. Test（杨钰婷，王永，周柚廷，陈杨洁，梁立，李惠茗，刘坤平．中国测试），2022，48（5）：65－71.

Lu Z W，Wu L，Dai X X，Wang Y Y，Sun M M，Zhou C L，Du H J，Rao H B．J. Hazard. Mater.，2021，402：123774.

Lu Z W，Lin X N，Zhang J J，Dai W L，Liu B C，Mo G Q，Ye J P，Ye J S．Electrochim. Acta，2019，295：514－523.

Zhang Y，Ai J X，Hu H L，Wang X，Zhou H X，Du K Z，Du H J，Yang Y．Appl. Phys. A，2022，128（4）：350.

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Preparation of a Novel Urchin-like Tungsten Copper Self-supporting Electrode for Enzymeless Glucose Sensing

Preparation and Application of a Chloramphenicol Electrochemical Sensor Based on Molecularly Imprinted Polymer

Detection of Hesperetin Using an Interconnected Porous Carbon Modified Electrode Based on Derivation of Potassium Sorbate

Progress in DNA Sequencing Based on Graphene Nanomaterials

In-situ Preparation of a Solid Phase Microextraction Probe Based on Graphene Self assembly and Its Application in Determination of Benzene Series in Water

Related Author

No data

Related Institution

Guangxi Key Laboratory of Agricultural Resources Chemistry and Biotechnology，Colleges and Universities Key Laboratory for Efficient Use of Agricultural Resources in the Southeast of Guangxi，College of Chemistry and Food Science，Yulin Normal University

Guangdong Food and Drug Vocational College

Zhaoqing Institute for Food Control

College of Environmental and Chemical Engineering， Zhaoqing University

湖北民族大学化学与环境工程学院

Address：100 Xianlie Middle Road, Guangzhou Postal code：510070
Tel：020-87684776,37656606 Fax：020-87684776 Email：fxcsxb@china.com
Technical support is provided by Beijing Founder electronics co., LTD 粤ICP备12017312号-3 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰