Determination of New Red in Beverages and Prepared Wines by HPLC－MS/MS with Solid Phase Extraction Based on Metal Organic Frameworks UiO－66－NH<sub>2</sub>

FENG Jun-jun; WANG Jing; ZHAO Lian-xing; JIANG Hai-yun; LIAN Ya-lin; TAN Tian-yu; ZHANG Fan; JING Zheng-yi; HE Feng; LI Teng-fei

doi:10.19969/j.fxcsxb.22110801

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Determination of New Red in Beverages and Prepared Wines by HPLC－MS/MS with Solid Phase Extraction Based on Metal Organic Frameworks UiO－66－NH₂

Scientific Papers | 更新时间：2023-04-17

- Determination of New Red in Beverages and Prepared Wines by HPLC－MS/MS with Solid Phase Extraction Based on Metal Organic Frameworks UiO－66－NH₂
- Journal of Instrumental Analysis Vol. 42, Issue 3, Pages: 299-306(2023)
- 作者机构：
  
  1.河北工程大学　生命科学与食品工程学院，河北邯郸 056038
  2.河北工程大学　材料科学与工程学院，河北邯郸 056038
  3.邯郸市食品药品检验中心，河北邯郸 056004
- 作者简介：
- 基金信息：
- DOI：10.19969/j.fxcsxb.22110801
  CLC：
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冯军军,王静,赵连兴等.基于UiO－66－NH₂金属有机框架材料的固相萃取/高效液相色谱－串联质谱法测定饮料和配制酒中的新红[J].分析测试学报,2023,42(03):299-306.

FENG Jun-jun,WANG Jing,ZHAO Lian-xing,et al.Determination of New Red in Beverages and Prepared Wines by HPLC－MS/MS with Solid Phase Extraction Based on Metal Organic Frameworks UiO－66－NH₂[J].Journal of Instrumental Analysis,2023,42(03):299-306.
冯军军,王静,赵连兴等.基于UiO－66－NH₂金属有机框架材料的固相萃取/高效液相色谱－串联质谱法测定饮料和配制酒中的新红[J].分析测试学报,2023,42(03):299-306. DOI： 10.19969/j.fxcsxb.22110801.

FENG Jun-jun,WANG Jing,ZHAO Lian-xing,et al.Determination of New Red in Beverages and Prepared Wines by HPLC－MS/MS with Solid Phase Extraction Based on Metal Organic Frameworks UiO－66－NH₂[J].Journal of Instrumental Analysis,2023,42(03):299-306. DOI： 10.19969/j.fxcsxb.22110801.

摘要

制备了一种新型固相萃取柱填料金属有机框架材料（MOFs）UiO－66－NH,2,，建立了固相萃取/高效液相色谱－串联质谱（SPE/HPLC－MS/MS）测定饮料和配制酒中新红的方法。通过扫描电子显微镜、红外光谱和氮气吸附－脱附等温线等手段表征材料的结构与吸附性能。采用Waters Atlantis,TM, T3（150 mm × 2.1 mm，3 μm）色谱柱，以10 mmol/L乙酸铵水溶液和甲醇为流动相进行分离，多反应监测（MRM）模式进行质谱检测。结果表明，在最佳萃取条件下，新红在0.05～10 mg/L范围内呈良好的线性关系，相关系数（,r,2,）为0.998，检出限（LOD）和定量下限（LOQ）分别为0.05 mg/L和0.15 mg/L。回收率为87.8%～107%，相对标准偏差（RSD，,n = ,6）为1.9%～11%，表明该方法具有较好的准确度和精密度。开发的基于UiO－66－NH,2,的固相萃取柱可作为一种高质量的吸附材料用于饮料和配制酒中新红的检测。

Abstract

A new type of solid phase extraction column filler metal organic frame material（MOFs） UiO－66－NH,2, was prepared，and a solid phase extraction/high performance liquid chromatography－tandem mass spectrometry（SPE/HPLC－MS/MS） was developed for the determination of new red in beverages and prepared wines. The structure and adsorption properties of UiO－66－NH,2, were characterized by scanning electron microscopy，infrared spectroscopy and nitrogen adsorption－desorption isotherm. The samples were separated on a Waters Atlantis,TM, T3（150 mm × 2.1 mm，3 μm） column with 10 mmol/L ammonium acetate aqueous solution and methanol as mobile phases，and analyzed in multiple reaction monitoring（MRM） mode. The results showed that，under the optimal extraction conditions，the calibration curves for new red showed good linearities in the range of 0.05－10 mg/L， with correlation coefficients（,r,2,） of 0.998.The limits of detection（LODs） and limits of quantitation（LOQs） were 0.05 mg/L and 0.15 mg/L，respectively. The recoveries of this method ranged from 87.8% to 107%， with relative standard deviations（RSDs，,n ,= 6） of 1.9%－11%， indicating that this method has good accuracy and precision. It is also proved that the UiO－66－NH,2, based solid phase extraction column could be used as a high quality adsorption material for detection of new red in beverages and prepared wines.

关键词

金属有机框架材料固相萃取高效液相色谱－串联质谱新红饮料配制酒

Keywords

metal organic frameworkssolid phase extractionhigh performance liquid chromatography－tandem mass spectrometrynew redbeverageprepared wines

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Determination of New Red in Beverages and Prepared Wines by HPLC－MS/MS with Solid Phase Extraction Based on Metal Organic Frameworks UiO－66－NH2

DOI：10.19969/j.fxcsxb.22110801

摘要

Abstract

关键词

Keywords

references

Determination of New Red in Beverages and Prepared Wines by HPLC－MS/MS with Solid Phase Extraction Based on Metal Organic Frameworks UiO－66－NH₂