Determination of Oxalic Acid in Urine Using an Electrochemical Alloy－Dealloying Prepared Platinum Nanoparticles Modified Electrode

SU Min; WANG Huan-huan; GUO Yu-hong; JIN Jun; YU Hao

doi:10.19969/j.fxcsxb.22060801

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Determination of Oxalic Acid in Urine Using an Electrochemical Alloy－Dealloying Prepared Platinum Nanoparticles Modified Electrode

Scientific Papers | 更新时间：2023-01-04

- Determination of Oxalic Acid in Urine Using an Electrochemical Alloy－Dealloying Prepared Platinum Nanoparticles Modified Electrode
- Journal of Instrumental Analysis Vol. 41, Issue 12, Pages: 1815-1821(2022)
- 作者机构：
  
  1.延安大学化学与化工学院，陕西延安 716000
  2.陕西省化学反应工程重点实验室，陕西延安 716000
- 作者简介：
- 基金信息：
- DOI：10.19969/j.fxcsxb.22060801
  CLC：
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苏敏,王焕焕,郭禹红等.电化学合金－去合金法制备铂纳米粒子电极检测尿液中草酸[J].分析测试学报,2022,41(12):1815-1821.

SU Min,WANG Huan-huan,GUO Yu-hong,et al.Determination of Oxalic Acid in Urine Using an Electrochemical Alloy－Dealloying Prepared Platinum Nanoparticles Modified Electrode[J].Journal of Instrumental Analysis,2022,41(12):1815-1821.
苏敏,王焕焕,郭禹红等.电化学合金－去合金法制备铂纳米粒子电极检测尿液中草酸[J].分析测试学报,2022,41(12):1815-1821. DOI： 10.19969/j.fxcsxb.22060801.

SU Min,WANG Huan-huan,GUO Yu-hong,et al.Determination of Oxalic Acid in Urine Using an Electrochemical Alloy－Dealloying Prepared Platinum Nanoparticles Modified Electrode[J].Journal of Instrumental Analysis,2022,41(12):1815-1821. DOI： 10.19969/j.fxcsxb.22060801.

摘要

采用电化学合金－去合金法制备Pt纳米粒子修饰玻碳电极（Pt NPs/GCE），用于尿液中草酸（OA）含量的电化学检测。先在同时含有Bi（NO,3,）,3,、K,2,PtCl,4,和EDTA的HClO,4,溶液中，于-0.4 V将Pt－Bi合金粒子沉积于电极表面，然后在HClO,4,溶液中于1.2 V下处理1 000 s可电化学溶出合金中的Bi，制得Pt NPs/GCE。采用扫描电镜法、EDS能谱法对电极表面修饰剂的组成和形貌进行表征。优化了电极的制备条件，并考察了OA在电极上的电化学行为。结果表明，OA在该电极上是一个扩散控制的不可逆氧化过程。电化学去合金后可得到一种多孔结构的Pt纳米粒子，增大了电极的活性面积，提高了对OA的电催化氧化活性。对电极制备条件的优化结果表明，当沉积液组成为1.0 mmol/L K,2,PtCl,6, + 3.0 mmol/L Bi（NO,3,）,3, + 3.0 mmol/L EDTA + 0.10 mol/L HClO,4,，合金沉积时间为500 s（-0.4 V），去合金时间为1 000 s（1.2 V）时，制备的修饰电极对OA具有良好的分析性能。在0.10 mol/L HClO,4,中，安培法检测OA的线性范围为2.0 × 10,-7,~ 4.9 × 10,-4, mol/L和4.9 × 10,-4, ~ 6.3 × 10,-3, mol/L，相关系数（,r,2,）分别为0.999 1和0.998 2，检出限（3,s,b,）可达2.7 ×10,-8, mol/L，对OA的灵敏度为83 μA/（mmol·L,-1,）。该电极具有、灵敏度高、线性范围宽和制备简单的特点，用于尿液中OA含量的测定，加标回收率为94.6% ~ 102%，相对标准偏差（RSD）为2.2% ~ 4.7%。

Abstract

A platinum nanoparticles modified glassy carbon electrode（Pt NPs/GCE） was fabricated by electrochemical alloy-dealloying method for the determination of oxalic acid（OA） in urine．The Pt－Bi alloy particles were electrochemically deposited on the electrode surface at -0.4 V in HClO,4, solution containing Bi（NO,3,）,3,，K,2,PtCl,4, and EDTA．Then Bi was electrochemically dissolved from the alloy at 1.2 V in HClO,4,，and Pt NPs/GCE was obtained. The composition and morphology of the modifier on the electrode surface were characterized by SEM and EDS techniques．Moreover，the electrochemical behavior of OA on this electrode was studied carefully based on the investigation of preparation conditions of the electrode．The results showed that the electrochemical behavior of OA on this electrode was a diffusion-controlled irreversible oxidation process．Benefiting from porous Pt NPs after electrochemical dealloying，this electrode had a larger active area，and thus had a high electrocatalytic activity for the oxidation of OA．The results of optimizing the electrode preparation showed that the modified electrode exhibited an excellent analytical performance for OA when the deposition solution was 1.0 mmol/L K,2,PtCl,6, + 3.0 mmol/L Bi（NO,3,）,3, + 3.0 mmol/L EDTA + 0.10 mol/L HClO,4,，the electrochemical alloy time was 500 s（-0.4 V），and the dealloying time was 1 000 s（1.2 V）．The linear ranges of amperometry determination for OA at 1.05 V in 0.10 mol/L HClO,4, were 2.0 × 10,-7,－4.9 × 10,-4, mol/L and 4.9 × 10,-4,－6.3 × 10,-3, mol/L，with correlation coefficients（,r,2,） of 0.999 1 and 0.998 2，respectively．The detection limit and sensitivity of the method for OA were 2.7 × 10,-8, mol/L（3,s,b,） and 83 μA/（mmol·L,-1,），respectively．Compared with other electrochemical sensors，this electrode had the characteristics of high sensitivity，wide linear range，as well as simple preparation．The electrode was applied to the determination of OA in urine with spiked recoveries of 94.6%－102% and RSDs of 2.2%－4.7%.

关键词

电化学合金－去合金Pt纳米粒子修饰电极草酸（OA）

Keywords

electrochemical alloy－dealloyingplatinum nanoparticlesmodified electrodeoxalic acid（OA）

references

Chen X H，Gu X J，Sun X Z，Zhang L，Xu Y．J. Clin. Ural. （陈雪花，顾晓箭，孙西钊，张犁，徐彦．临床泌尿外科杂志），2013，28（6）：437－439.

Zhai Q Z，Zhang X X，Liu Q Z．Spectrochim. Acta A，2006，65：1－4.

Hang Y P，Lu Z L Z，Yang C Y．J. Instrum. Anal. （杭义萍，卢祝靓子，杨春英．分析测试学报），2014，33（11）：1307－1311.

Munoz J A，Lopez－Mesas M，Valiente M．Talanta，2010，81：392－397.

Ma Y，Lian S，Huang Z Y，Peng A H，Lin Z Z，Chen X M．Sci. Sin. Chem. （马颖，练赛，黄志勇，彭爱红，林郑忠，陈晓梅．中国科学：化学），2016，46（3）：287－293.

Raoof J B，Chekinb F，Ehsani V．Sens. Actuators B，2015，207：291－296.

Liu Y，Huang J S，Wang D W，Hou H Q，You T Y．Anal. Methods，2010，2：855－859.

Ahmar H，Fakhari A R，Nabid M R，Tabtabaei－Rezaei S J，Bide Y．Sens. Actuators B，2012，171/172：611－618.

Shaidarova L G，Gedmina A V，Chelnokova I A，Budnikov G K．J. Anal. Chem.，2003，58（9）：886－891.

Bern A，Rodes A，Feliu J M．J. Electroanal. Chem.，2004，563：49－62.

Luo X L，Chen L M，Yang J Y，Li S T，Li M T，Mo Q，Li Y B，Li X C．Microchem. J.，2021，169：106623.

Wei F C，Ou P P，Wu Y Y，Wu J W，Lin Y，Du F K，Tan X C．J. Instrum. Anal. 韦富存，欧盼盼，吴叶宇，吴佳雯，林瑜，杜方凯，谭学才．分析测试学报），2021，40（7）：996－1003.

Rostami S，Azizi S N，Ghasemi S．J. Electroanal. Chem.，2017，788：235－245.

Alizadeh T，Nayeri S．Mater. Sci. Eng. C，2019，100：826－836.

Hussain S，Zaidi S A，Vikraman D，Kim H S，Jung J W．Microchem. J.，2020，159：105404.

Araujo E G，Oliveira G R，Santos E V，Martinez－Huitle C A，Panizza M，Fernandes N S．J. Electroanal. Chem.，2013，701：32－35.

Zheng Y Q，Yang C Z，Pu W H，Zhang J D．Food Chem.，2009，114：1523－1528.

Fang Y S，Xu X Y，Guo X Q，Cui B，Wang L S．Anal. Bioanal. Chem.，2020，412：5719－5727.

Chen X M，Cai Z X，Huang Z Y，Oyama M，Jiang Y Q，Chen X．Nanoscale，2013，5：5779－5783.

Ma L，Zeng Q，Zhang M，Wang L S，Cheng F L．J. Exp. Nanosci.，2016，11：1242－1252.

Kim W Y，Lee J S，Shin D H，Jang J．J. Mater. Chem. B，2018，6：1272－1278.

Xu Y，Zhang B．Chem. Soc. Rev.，2014，43：2439－2450.

Weremfo A，Clara－Fong S T，Khan A，Hibbert D B，Zhao C．Electrochim. Acta，2017，231：20－26.

An Y L，Tian Y，Wei C L，Tao Y，Xi B J，Xiong S L，Feng J K，Qian Y T．Nano Today，2021，37：101094.

Gao J J，Zhou G P，Qiu H J，Wang Y，Wang J Q．Corros. Sci.，2016，108：194－199.

Beluomini M A，Stradiotto N R，Boldrin Zanoni M V．J. Electroanal. Chem.，2022，904：115866.

Sabria Y M，Mohibul Kabira K M，Kandjania A E，Bhargava S K．Sens. Actuators B，2017，245：273－281.

Li Y J，Gao W，Ci L J，Wang C M，Ajayan P M．Carbon，2010，48：1124－1130.

Chollier－Brym M J，Epron F，Lamy－Pitara E，Barbier J．J. Electroanal. Chem.，1999，474：147－154.

Chen J H，Gu G Y，Wang Y L．Chin. J. Clin. Lab. Sci. （陈军浩，顾光煜，王以立．临床检验杂志），1999，17（5）：266－268.

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