Determination of Organophosphorus Amino Acids Herbicides Residues in Fruits and Vegetables by Underivatization/Liquid Chromatography－Tandem Mass Spectrometry

LIN Li-min; ZHANG Jian-ying; XIAO Feng; HUANG Ke; YE Gang; HONG Xiao-liu; LÜ Fei

doi:10.19969/j.fxcsxb.22042805

您当前的位置：

首页 >

文章列表页 >

Determination of Organophosphorus Amino Acids Herbicides Residues in Fruits and Vegetables by Underivatization/Liquid Chromatography－Tandem Mass Spectrometry

Experimental Techniques and Methods | 更新时间：2023-01-04

- Determination of Organophosphorus Amino Acids Herbicides Residues in Fruits and Vegetables by Underivatization/Liquid Chromatography－Tandem Mass Spectrometry
- Journal of Instrumental Analysis Vol. 41, Issue 11, Pages: 1702-1706(2022)
- 作者机构：
  
  1.深圳海关食品检验检疫技术中心，广东深圳 518045
  2.惠州海关技术中心，广东惠州 516006
- 作者简介：
- 基金信息：
- DOI：10.19969/j.fxcsxb.22042805
  CLC：
扫描看全文
林丽敏,张建莹,肖锋等.非衍生化/液相色谱－串联质谱法测定果蔬中氨基酸类有机磷除草剂残留[J].分析测试学报,2022,41(11):1702-1706.

LIN Li-min,ZHANG Jian-ying,XIAO Feng,et al.Determination of Organophosphorus Amino Acids Herbicides Residues in Fruits and Vegetables by Underivatization/Liquid Chromatography－Tandem Mass Spectrometry[J].Journal of Instrumental Analysis,2022,41(11):1702-1706.
林丽敏,张建莹,肖锋等.非衍生化/液相色谱－串联质谱法测定果蔬中氨基酸类有机磷除草剂残留[J].分析测试学报,2022,41(11):1702-1706. DOI： 10.19969/j.fxcsxb.22042805.

LIN Li-min,ZHANG Jian-ying,XIAO Feng,et al.Determination of Organophosphorus Amino Acids Herbicides Residues in Fruits and Vegetables by Underivatization/Liquid Chromatography－Tandem Mass Spectrometry[J].Journal of Instrumental Analysis,2022,41(11):1702-1706. DOI： 10.19969/j.fxcsxb.22042805.

摘要

建立了果蔬中4种氨基酸类有机磷除草剂的非衍生化/液相色谱－串联质谱分析方法。样品采用水－二氯甲烷混合溶液提取，经二氯甲烷液液萃取法结合HLB固相萃取柱净化后，进行液相色谱－串联质谱测定。最佳实验条件下，4种化合物在0.010 ~ 0.200 mg/L质量浓度范围内呈良好线性关系，相关系数（,r,）均大于0.996，方法检出限为0.01 mg/kg，定量下限为0.05 mg/kg。在0.050、0.100、0.200 mg/kg 3个加标水平下的平均回收率为72.2% ~ 109%，相对标准偏差（RSD，,n ,= 6）为2.2% ~11%。该方法快速、简便、灵敏、准确，可用于水果、蔬菜中氨基酸类有机磷除草剂的定量检测和确证。

Abstract

An underivatization/liquid chromatography－tandem mass spectrometric method was developed for the determination of 4 organophosphorus amino acids herbicides in fruits and vegetables．Samples were firstly extracted with water－dichloromethane solution，then purified by dichloromethane liquid－liquid extraction with HLB solid phase extraction column，and finally determined by liquid chromatography－mass spectrometry．At the optimal conditions，the linear correlation coefficients（,r,） for all compounds were more than 0.996 in the concentration range of 0.010－0.200 mg/L．The limits of detection and quantitation of the method were 0.01 mg/kg and 0.05 mg/kg，respectively．The average recoveries for all compounds at spiked levels of 0.050，0.100 and 0.200 mg/kg ranged from 72.2% to 109%，with relative standard deviations（RSDs，,n ,= 6） of 2.2%－11%．The method is rapid，simple，sensitive and accuracy，and it could be used for the determination and confirmation of organophosphorus amino acids herbicides in fruits and vegetables.

关键词

非衍生化氨基酸类有机磷除草剂液相色谱－串联质谱

Keywords

underivatizationorganophosphorus amino acids herbicidesliquid chromatography－tandem mass spectrometry

references

Yang Y J，Zhang B．World Pestic. （杨益军，张波．世界农药），2021，43（4）：19.

Luo Y F，Zhang J F．Chin. J. Disaster Med. （罗毅沣，张剑锋．中华灾害救援医学），2021，9（8）：1194－1196.

Zhang J．Pestic. Sci. Adm. （张静．农药科学与管理），2017，38（5）：5.

European Food Safety Authority（EFSA）．EFSA J.，2019，17（10）：5862.

GB 2763－2021．National Food Safety Standard—Maximum Residue Limits for Pesticides in Food. National Standards of the People’s Republic of China（食品安全国家标准食品中农药最大残留限量．中华人民共和国国家标准）.

Bienvenu J F，Bélanger P，Gaudreau É，Provencher G，Fleury N．Anal. Bioanal. Chem.，2021，413：2225－2234.

Wei F，Tang J，Mao F F，Huang S，Cui H S．Chem. Anal. Meterage（魏峰，汤杰，毛芳芳，黄升，崔海松．化学分析计量），2019，28（6）：113－117.

Gotti R，Fiori J，Bosi S，Dinelli G．J. Chromatogr. A，2019，1601：357－364.

Luo T，Fu W W，Guo L Y，Wang H X，Wen H．J. Food Saf. Qual. （罗彤，付文雯，郭卢云，王会霞，文红．食品安全质量检测学报），2018，9（1）：161－166.

Luo T，Fu W W，Guo L Y，Wang H X．Food Res. Dev. （罗彤，付文雯，郭卢云，王会霞．食品研究与开发），2018，39（14）：153－158.

Zhang Y F，Zhao S，Chang J，Ren X X，Wang A H，Zhao P，Dong L P，Wu X J，Zhang J R，Liu B J．J. Instrum. Anal. 张云峰，赵森，常靖，任昕昕，王爱华，赵鹏，董林沛，吴小军，张景然，刘冰洁．分析测试学报），2021，40（4）：571－576.

Jake C，Ulrich P，Lee F．Anal. Bioanal. Chem.，2021，（413）：3763－3774.

Zhou Q，W Y M．Chin. Agric. Sci. Bull. （周芹，吴玉梅．中国农学通报），2020，36（27）：72－80.

Zhao J Y，Wei F，Yu Q H，Hu B Z．J. Food Saf. Qual. （赵佳胤，魏峰，俞秋红，胡贝贞．食品安全质量检测学报），2020，11（20）：7222－7328.

Pan S D，Tong T D，Ye M J，Chen X H，Jin M C．Chin. J. Chromatogr. （潘胜东，童廷德，叶美君，陈晓红，金米聪．色谱），2019，37（12）：1321－1330.

Zhu J J，Sun W S，Zhou T T，Dong Y J，Zhong H H，Huang R B，Wu D H，Xu Z J，Zhang H．Chin. Agric. Bioprocess Eng. （诸骏杰，孙文闪，周婷婷，董叶箐，钟寒辉，黄荣博，吴丹虹，徐子健，章虎．生物加工过程），2020，36（27）：72－80.

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Determination of Iminoctadine Residues in Fruits and Vegetables by Solid Phase Extraction and Liquid Chromatography－ Tandem Mass Spectrometry

Determination of Total Haloxyfop in Plant-derived Foods by Liquid Chromatography－Tandem Mass Spectrometry

Simultaneous Determination of Xylazine and Its Metabolite 2，6-Dimethylaniline in Pork by QuEChERS／Liquid Chromatography－Tandem Mass Spectrometry

Determination of 7 Antioxidants in Rubber Seal Gaskets for Food Contact by Liquid Chromatography－Tandem Mass Spectrometry

Related Author

No data

Related Institution

Technical Center of Nanning Customs District

Center for Comprehensive Technology of Guiyang Customs

Guizhou Light Industrial Vocational College

Key Laboratory of Industrial Ecology and Environmental Engineering（MOE）， School of Environmental Science & Technology， Dalian University of Technology

Department of Packaging Engineering， School of Mechanical Engineering， Jiangnan University

Address：100 Xianlie Middle Road, Guangzhou Postal code：510070
Tel：020-87684776,37656606 Fax：020-87684776 Email：fxcsxb@china.com
Technical support is provided by Beijing Founder electronics co., LTD 粤ICP备12017312号-3 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰