Rapid Screening and Confirmation of 222 Pesticide Residues in Agricultural Products by Gas Chromatography－Electrostatic Field Orbitrap High Resolution Mass Spectrometry

YIN Xue-yan; ZHU Jia-ming; DU Yan-yu; WANG Jie-qiong; ZHAI Yun-zhong

doi:10.19969/j.fxcsxb.21052101

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Rapid Screening and Confirmation of 222 Pesticide Residues in Agricultural Products by Gas Chromatography－Electrostatic Field Orbitrap High Resolution Mass Spectrometry

Scientific Papers | 更新时间：2023-01-04

- Rapid Screening and Confirmation of 222 Pesticide Residues in Agricultural Products by Gas Chromatography－Electrostatic Field Orbitrap High Resolution Mass Spectrometry
- Journal of Instrumental Analysis Vol. 41, Issue 2, Pages: 172-186(2022)
- 作者机构：
  
  常州市农产品质量安全中心，江苏常州 213002
- 作者简介：
- 基金信息：
- DOI：10.19969/j.fxcsxb.21052101
  CLC：
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殷雪琰,朱佳明,堵燕钰等.基于气相色谱－静电场轨道阱高分辨质谱法快速筛查和确证农产品中222种农药残留[J].分析测试学报,2022,41(02):172-186.

YIN Xue-yan,ZHU Jia-ming,DU Yan-yu,et al.Rapid Screening and Confirmation of 222 Pesticide Residues in Agricultural Products by Gas Chromatography－Electrostatic Field Orbitrap High Resolution Mass Spectrometry[J].Journal of Instrumental Analysis,2022,41(02):172-186.
殷雪琰,朱佳明,堵燕钰等.基于气相色谱－静电场轨道阱高分辨质谱法快速筛查和确证农产品中222种农药残留[J].分析测试学报,2022,41(02):172-186. DOI： 10.19969/j.fxcsxb.21052101.

YIN Xue-yan,ZHU Jia-ming,DU Yan-yu,et al.Rapid Screening and Confirmation of 222 Pesticide Residues in Agricultural Products by Gas Chromatography－Electrostatic Field Orbitrap High Resolution Mass Spectrometry[J].Journal of Instrumental Analysis,2022,41(02):172-186. DOI： 10.19969/j.fxcsxb.21052101.

摘要

该文在QuEChERS方法的基础上采用固相分散萃取样品处理一体机（Sio－dSPE）对样品进行前处理，结合气相色谱－静电场轨道阱高分辨质谱法（GC－Orbitrap MS）对农产品中多农药残留进行筛查和确证。对Sio－dSPE前处理方法中盐析剂和除水剂的种类、净化剂的种类与用量、基质效应等进行考察。在最优条件下，采用GC－Orbitrap MS对农产品中222种农药残留进行检测，线性范围为1～200 μg/L，在莴苣、大米和茶叶中的定量下限分别为0.5～5 μg/kg、1～10 μg/kg、2.5～25 μg/kg。在上述3种基质中分别进行10、20、50 μg/kg浓度水平的加标回收实验，测得回收率分别为70.5%～121%、70.2%～119%、65.2%～125%，相对标准偏差（RSD）分别不大于11%、10%、12%。该方法具有样品处理简单、分析时间短、净化效果好等优点，适用于农产品中多农药残留的快速筛查与定量。

Abstract

A gas chromatography－electrostatic field orbitrap high resolution mass spectrometry（GC－Orbitrap MS） was developed for the rapid screening and confirmation of 222 kinds of pesticide residues in agricultural products，based on QuEChERS method. The samples were preprocessed with an integrated solid phase dispersion extraction sample processing machine（Sio－dSPE）. Experimental conditions including types of salting-out agent and water removal agent，type of cleaning agent and its amount，matrix effect were investigated and optimized in detail. Under the optimized conditions，the linear ranges of 222 pesticides were in the range of 1-200 μg/L，the average recoveries for 222 pesticide residues in lettuce，rice and tea samples at three spiked levels of 10，20 and 50 μg/kg were in the ranges of 70.5%－121%，70.2%－119% and 65.2%－125%，with their relative standard deviations（RSDs） not more than 11%，10% and 12%，respectively. The limits of quantitation（LOQs） of this method for lettuce，rice and tea were 0.5－5 μg/kg，1－10 μg/kg and 2.5－25 μg/kg，respectively. With the advantages of simplicity，easy pretreatment and high purifying efficiency，the method was suitable for the fast screening and confirmation of pesticide residues in agricultural products.

关键词

气相色谱－静电场轨道阱高分辨质谱法（GC－Orbitrap MS）固相分散萃取样品处理一体机法（Sio－dSPE）快速筛查和确证多农药残留农产品

Keywords

gas chromatography－electrostatic field orbitrap high resolution mass spectrometry （GC－Orbitrap MS）solid phase dispersion extraction sample processing machine（Sio－dSPE）rapid screening and confirmationmulti-pesticide residuesagricultural product

references

Pang G F，Fan C L，Chang Q Y，Li J X，Kang J，Lu M L．J. AOAC Int.，2018，101（4）：1156－1182.

GB 2763－2021．National Food Safety Standard－Maximum Residue Limits for Pesticides in Food．National Standards of the People's Republic of China（食品安全国家标准食品中农药最大残留限量．中华人民共和国国家标准）.

Ioannis N P，Nikolaos S T，Efrosini A P．Microchem. J.，2013，108（11）：1－6.

Disni D，Champika T，Azeez M，Lindsey M，Jill R，Tang H，Feng J，Della W M S，WongY C．Food Res. Int.，2013，53（2）：931－937.

Han M，Hou X，Qiu S T，Wang Y H．China Meas. Test（韩梅，侯雪，邱世婷，王悦涵．中国测试），2020，46（5）：65－71，76.

Mojtaba S，Najmeh Y，Mahnaz G．Food Chem.，2016，204（1）：289－297.

Faraji M，Noorbakhsh R，Shafieyan H，Ramezani M．Food Chem.，2018，240：634－641.

Cheng Z P，Dong F S，Xu J，Liu X G，Wu X H，Chen Z L，Pan X L，Gan J，Zheng Y Q．Food Chem.，2017，231：365－373.

Gerardo M D，Roberto R G，Antonia G F．Food Chem.，2016，197：907－915.

EC 657－2002．Implementing Council Directive 96/23/EC Concerning the Performance of Analytical Methods and the Interpretation of Results．

AOAC Official Method 2007. 01．Pesticide Residues in Foods by Acetonitrile Extraction and Partitioning with Magnesium Sulfate Gas Chromatography/Mass Spectrometry and Liquid Chromatography/Tandem Mass Spectrometry.

EN 15662：2008．Foods of Plant Origin－Determination of Pesticide Residues Using GC－MS and/or LC－MS/MS Following Acetonitrile Extraction/Partitioning and Clean Up by Dispersive SPE－QuEChERS－Method．British Standard.

Chen X，Dong Z L，Sun Y Y，Shang B Y，Liu J C，Qu S C，Ji M S．J. Instrum. Anal. 陈溪，董振霖，孙玉玉，尚宝玉，刘佳成，曲世超，纪明山．分析测试学报），2016，35（4）：394－399.

Yin X Y，Jiang Z G，Du Y Y，Luo Y L，Wang J Q，Zhai Y Z．J. Food Saf. Qual. （殷雪琰，蒋治国，堵燕钰，罗漪涟，王洁琼，翟云忠．食品安全质量检测学报），2016，7（12）：5009－5106.

Ruan H，Rong W G，Ma Y J，Ji W L，Liu H L，Song N H．Chin. J. Chromatogr. （阮华，荣维广，马永建，吉文亮，刘华良，宋宁慧．色谱），2013，31（12）：1211－1217.

Meng Z J，Huang Y X，Di P Y，Zhao L M，Niu L S，Fan S F，Li Q，Zhang Y．Food Sci. 孟志娟，黄云霞，邸鹏月，赵丽敏，牛立沙，范素芳，李强，张岩．食品科学），2020，41（16）： 272－285.

Meng Z J，Sun W Y，Zhao L M，Huang Y X，Ma J M，Fang S F，Li Q，Zhang Y，Pan C P．Chin. J. Anal. Chem.

孟志娟，孙文毅，赵丽敏，黄云霞，马俊美，范素芳，李强，张岩，潘灿平．分析化学），2019，47（8）：1227－1234.

Li A P，He J Q，Yang P R，Jin H Y，Song P S．Chin. J. Pharm. Anal. （李安平，贺军权，杨平荣，金红宇，宋平顺．药物分析杂志），2019，39（8）：1463－1481.

Zhou J J，Hou Y L，Huang W，Yang C，Jin Y．Mod. Agrochem. （周进杰，侯亚龙，黄伟，杨程，金盈．现代农药），2018，17（3）：38－42.

Hou X，Yi S G，Han M，Qiu S T．Mod. Sci. Instrum. 侯雪，易盛国，韩梅，邱世婷．现代科学仪器），2012，（4）：115－118.

Jiang K L，Hu B，Wu X Q，Xie Y J，Li T M，Fan C L，Wang M L，Wang W W，Chen H．J. Instrum. Anal. 蒋康丽，扈斌，吴兴强，谢瑜杰，李铁梅，范春林，王明林，王雯雯，陈辉．分析测试学报），2021，40（9）：1257－1270.

Bi J，Ren J，Zhao Y F，Chen D W．J. Instrum. Anal. （毕军，任君，赵云峰，陈达炜．分析测试学报），2021，40（9）：1318－1327.

Pang G F，Chang Q Y，Bai R B，Fan C L，Zhang Z J，Yan H Y，Wu X Q．Food Saf. Health，2020，6（4）：432－441.

Du Q Y，Zhang Y F，Wang J F，Wang L，Chang J，Dong L P，Wu X J，Liu B J．J. Instrum. Anal. （杜秋瑶，张云峰，王继芬，王璐，常靖，董林沛，吴小军，刘冰洁．分析测试学报），2020，39（4）：485－491.

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