Determination of 16 Elements in Ti65 High Temperature Titanium Alloy by Inductively Coupled Plasma Atomic Emission Spectrometry

YAN Peng-fei; ZANG Xu; SONG Ti-jie; ZHAO Zheng-xin; YU Yan-yan; LIU Xi-shan

doi:10.12452/j.fxcsxb.240626173

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Determination of 16 Elements in Ti65 High Temperature Titanium Alloy by Inductively Coupled Plasma Atomic Emission Spectrometry

Aerospace New Materials Testing Column | 更新时间：2024-11-04

- Determination of 16 Elements in Ti65 High Temperature Titanium Alloy by Inductively Coupled Plasma Atomic Emission Spectrometry
- Journal of Instrumental Analysis Vol. 43, Issue 9, Pages: 1348-1355(2024)
- 作者机构：
  
  1.沈阳飞机工业（集团）有限公司，辽宁沈阳 110850
  2.空军装备部驻沈阳地区军事代表局驻沈阳地区第一军事代表室，辽宁沈阳 110850
  3.中国航发北京航空材料研究院，北京 100095
- 作者简介：
- 基金信息：
- DOI：10.12452/j.fxcsxb.240626173
  CLC： O657.3;TG132.3
- Published：15 September 2024，
  
  Received：26 June 2024，
  
  Revised：21 July 2024，
- 稿件说明：
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严鹏飞,臧旭,宋体杰,赵政鑫,于妍妍,刘喜山.电感耦合等离子体原子发射光谱法测定Ti65高温钛合金中16种元素[J].分析测试学报,2024,43(09):1348-1355.

YAN Peng-fei,ZANG Xu,SONG Ti-jie,ZHAO Zheng-xin,YU Yan-yan,LIU Xi-shan.Determination of 16 Elements in Ti65 High Temperature Titanium Alloy by Inductively Coupled Plasma Atomic Emission Spectrometry[J].Journal of Instrumental Analysis,2024,43(09):1348-1355.
严鹏飞,臧旭,宋体杰,赵政鑫,于妍妍,刘喜山.电感耦合等离子体原子发射光谱法测定Ti65高温钛合金中16种元素[J].分析测试学报,2024,43(09):1348-1355. DOI： 10.12452/j.fxcsxb.240626173.

YAN Peng-fei,ZANG Xu,SONG Ti-jie,ZHAO Zheng-xin,YU Yan-yan,LIU Xi-shan.Determination of 16 Elements in Ti65 High Temperature Titanium Alloy by Inductively Coupled Plasma Atomic Emission Spectrometry[J].Journal of Instrumental Analysis,2024,43(09):1348-1355. DOI： 10.12452/j.fxcsxb.240626173.

摘要

以盐酸-氢氟酸-硝酸混合酸体系溶解样品，建立了电感耦合等离子体原子发射光谱（ICP-AES）测定Ti65钛合金中Al、Sn、Zr、Mo、Si、Ta、Nb、W 8种合金元素以及Cr、Mn、Cu、Ni、B、Y、Re、Fe 8种杂质元素含量的分析方法。考察了钛基体和共存元素对待测元素的影响以及硅标准溶液基体对Al元素测定的影响，采用基体匹配法消除了基体效应的影响，并通过合金元素匹配消除了光谱干扰。优化的仪器分析参数为高频功率1.2 kW，雾化气压力200 kPa。在优化实验条件下建立工作曲线，其线性相关系数均不小于0.998 7，各元素的检出限为0.000 03%～0.010%。采用该方法测定钛合金标准样品以及配制的Ti65钛合金模拟样品，实验结果与理论值相吻合。实验结果的相对标准偏差在8.6%以内，加标回收率为98.0%～104%。

Abstract

By dissolving the Ti65 samples with HCl，HF and HNO

system，amounts of 8 alloy elements（Al，Sn，Zr，Mo，Si，Ta，Nb，W） and amounts of 8 impurity elements（Cr，Mn，Cu，Re，Ni，B，Y，Fe） were determined by inductively coupled plasma atomic emission spectroscopy（ICP-AES）. The influence of titanium matrix and coexisting elements on the measured elements and the influence of silicon standard solution matrix on the determination of Al elements were investigated. Matrix matching method was used to eliminate the influence of matrix effect and alloy element matching method was used to eliminate the spectral interference. The analysis parameters of the instrument were optimized，and the high generator power was 1.2 kW and the nebulizer gas pressure was 200 kPa. The working curve is established under the selected experimental conditions.The linear correlation coefficients of the calibration curve were not less than 0.998 7，and the limits of detection of method were between 0.000 03% and 0.010%. Test results of titanium CRMs and simulated Ti65 samples were consistent with the theoretical values. The relative standard deviations（RSDs） of the test results were not more than 8.6%，and the recoveries were in the range of 98.0%-104%.

关键词

Ti65高温钛合金电感耦合等离子体原子发射光谱法（ICP-AES）化学成分

Keywords

Ti65high temperature titanium alloyinductively coupled plasma atomic emission spectroscopy（ICP-AES）chemical composition

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