Determination of Dechlorane Plus Derivatives in Recycled Polymer Material by Pyrolysis-Gas Chromatography-Tandem Mass Spectrometry

ZHANG Zi-hao; HUO Wei-jiang; WANG Jing; XIAO Qian; LIU Ying-feng; LI Quan-zhong; ZHENG Jian-guo

doi:10.12452/j.fxcsxb.24032501

您当前的位置：

首页 >

文章列表页 >

Determination of Dechlorane Plus Derivatives in Recycled Polymer Material by Pyrolysis-Gas Chromatography-Tandem Mass Spectrometry

Scientific Papers | 更新时间：2024-08-08

- Determination of Dechlorane Plus Derivatives in Recycled Polymer Material by Pyrolysis-Gas Chromatography-Tandem Mass Spectrometry
- Journal of Instrumental Analysis Vol. 43, Issue 8, Pages: 1265-1272(2024)
- 作者机构：
  
  广州海关技术中心，广东广州 510623
- 作者简介：
- 基金信息：
- DOI：10.12452/j.fxcsxb.24032501
  CLC： O657.7;X132
- Published：15 August 2024，
  
  Received：25 March 2024，
  
  Revised：17 May 2024，
- 稿件说明：
移动端阅览
张子豪,霍炜江,王晶,肖前,刘莹峰,李全忠,郑建国.基于热解分离-气相色谱-串联质谱技术测定聚合物再生原料中得克隆类衍生物[J].分析测试学报,2024,43(08):1265-1272.

ZHANG Zi-hao,HUO Wei-jiang,WANG Jing,XIAO Qian,LIU Ying-feng,LI Quan-zhong,ZHENG Jian-guo.Determination of Dechlorane Plus Derivatives in Recycled Polymer Material by Pyrolysis-Gas Chromatography-Tandem Mass Spectrometry[J].Journal of Instrumental Analysis,2024,43(08):1265-1272.
张子豪,霍炜江,王晶,肖前,刘莹峰,李全忠,郑建国.基于热解分离-气相色谱-串联质谱技术测定聚合物再生原料中得克隆类衍生物[J].分析测试学报,2024,43(08):1265-1272. DOI： 10.12452/j.fxcsxb.24032501.

ZHANG Zi-hao,HUO Wei-jiang,WANG Jing,XIAO Qian,LIU Ying-feng,LI Quan-zhong,ZHENG Jian-guo.Determination of Dechlorane Plus Derivatives in Recycled Polymer Material by Pyrolysis-Gas Chromatography-Tandem Mass Spectrometry[J].Journal of Instrumental Analysis,2024,43(08):1265-1272. DOI： 10.12452/j.fxcsxb.24032501.

摘要

采用分步热解分离-气相色谱-串联质谱（EGA-GC-MS/MS）建立了快速测定固体聚合物再生原料（再生纸浆、再生塑料）中6种新发的得克隆类衍生物的方法。样品预先切割成小块，在裂解仪中程序加热升温，使得克隆类衍生物于聚合物裂解前气化析出，以ZB-5HT石英毛细管柱为分离柱，在多反应监测（MRM）模式下使用内标法进行质谱测定。对热解分离条件、色谱和质谱条件进行了优化，在最佳实验条件下，6种得克隆类衍生物在10.0～500 μg/g范围内具有良好的线性关系，定量下限为4.5~11.4 mg/kg。再生纸浆的加标回收率为85.3%～113%，相对标准偏差（RSD，

=6）不大于6.4%；再生塑料聚合物的加标回收率为86.2%～116%，RSD（

=6）不大于7.2%。该方法无需冷冻粉碎、萃取等步骤，可直接进样分析，具有操作简便快速、灵敏度高等优点，适用于固体聚合物再生原料中得克隆类衍生物的测定。

Abstract

A method for determination of dechlorane plus derivatives in solid polymer recycled materials （recycled pulp，recycled plastics） was established by stepwise pyrolysis-gas chromatography-tandem mass spectrometry（EGA-GC-MS/MS）. Sample were cut up in advance and heated in the pyrolysis furnace. 6 dechloraneplus derivatives were evolving before polymer pyrolysis. The dechloraneplus derivatives were separated by ZB-5HT INFERNO column，and analyzed

using tandem mass spectrometry employing the internal standard method and multi-reaction monitoring mode （MRM）. In this paper，pyrolysis and chromatography-mass spectrometry conditions were optimized. Under the optimized experimental conditions，a linear correlation of 6 dechlorane plus derivatives was observed between 10.0-500 μg/g，and quantitation limits were 4.5-11.4 mg/kg. Recycling pulp samples yielded recoveries ranging from 85.3%-113%，with relative standard deviations（RSDs） not higher than 6.4%. Recoveries of plastic polymer samples were 86.2%-116% with their RSDs（

=6） not higher than 7.2%. The sample can be directly injected for analysis without pre-treatment such as freezing，grinding and extraction. This method is simple，rapid and sensitive，which is suitable for qualitative analysis and determination of dechlorane plus derivatives from solid polymer regenerated raw materials.

关键词

再生塑料再生纸浆得克隆类衍生物逸出气体分析气相色谱-串联质谱

Keywords

reprocessed plasticrecycled pulpsdechlorane plus derivativesevolving gas analysisgas chromatography-tandem mass spectrometry

references

Huo W J，Zhang Z H，Wen X K，Peng S B，Yu J L. Chem. Res. Appl.（霍炜江，张子豪，温信凯，彭速标，余建龙. 化学研究与应用），2023，35（3）：727-731.

Hoh E，Zhu L Y，Hites R A. Environ. Sci. Technol.，2006，40（4）：1184-1189.

Chen K H，Zheng J，Yan X，Yu L H，Luo X J，Peng X W，Yu Y J，Yang Z Y，Mai B X. Chemosphere，2015，123：43-47.

Liu H Y，Luo X J. Asian J. Ecotoxicol.（刘红英，罗孝俊. 生态毒理学报），2022，17（1）：47-59.

Li Y L，Meng X Z，Zhao L F，Chen L. Environ. Sci. Technol.（李宇霖，孟祥周，赵丽芳，陈玲. 环境科学与技术），2012，35（2）：79-83.

Li B H，Chen J J，Du Q Y，Wang B B，Qu Y，Chang Z J. Chemosphere，2020，249：126481.

Yang Y，Ji F N，Cui Y B，Li M. Chemosphere，2016，144：2476-2481.

Ministry of Ecology and Environment of the People’s Republic of China. Priority Control List of New Pollutants （2023 version）（中华人民共和国生态环境部. 重点管控新污染物清单（2023年版））. ［2022-12-29］. https：//www.mee.gov.cn/xxgk2018/xxgk/xxgk02/202212/t20221230_1009167.htmlhttps://www.mee.gov.cn/xxgk2018/xxgk/xxgk02/202212/t20221230_1009167.html.

Ren N Q，Sverko E，Li Y F，Zhang Z，Harner T，Wang D G，Wan X N，Mccarry B. Environ. Sci. Technol.，2008，42（17）：6476-6480.

Qi H，Huang J，Shen J M，Liu L Y，Li Y F. J. Harbin Inst. Technol.（齐虹，黄俊，沈吉敏，刘丽艳，李一凡. 哈尔滨工业大学学报），2010，42（6）：995-999.

Wei W，Na G S，He C X，Ma X D，Gao H，Fang X D，Yao Z W，Zhou C G. Chin. J. Anal. Lab. （魏葳，那广水，赫春香，马新东，高会，方小丹，姚子伟，周传光. 分析试验室），2014，33（2）：162-166.

Wang D G，Yang M，Qi H，Sverko E，Ma W L，Li Y F，Alaee M，Reiner E J，Shen L. Environ. Sci. Technol.，2010，44（17）：6608-6613.

Guo X C，Rao Z，Li X J，Li N，Tian Q，Pan M，Tong L，Yang Z P，Tian F F. J. Instrum. Anal.（郭晓辰，饶竹，李晓洁，黎宁，田芹，潘萌，佟玲，杨志鹏，田菲菲. 分析测试学报），2019，38（2）：141-147.

Zhao T，Tang H，Chen D Z，Huo F F，Li L. Anal. Methods，2017，9（7）：1168-1176.

Chen C L，Tsai D Y，Ding W H. Food Chem.，2014，164：286-292.

Roscales J L，Vicente A，Ramos L，Jiménez B. Anal. Bioanal. Chem.，2017，409（20）：4905-4913.

Zhang Z W，Pei N C，Sun Y X，Li J L，Li X P，Yu S，Xu X R，Hu Y X，Mai B X. Environ. Res.，2019，171：145-152.

Peng Y，Wu J P，Luo X J，Zhang X W，Giesy L P，Mai B X. Environ. Int.，2019，130：104952.

Ren G F，Yu Z Q，Ma S T，Li H，Peng G Y，Sheng G Y，Fu J. Environ. Sci. Technol.，2009，43（24）：9453-9457.

Zhang H，Bayen S，Kelly B. Sci. Total Environ.，2015，523：219-232.

Zhou S N，Reiner E J，Marvin C H，Helm P A，Shen L，Brindle L D. Rapid Commun. Mass Spectrom.：RCM，2011，25（3）：436-442.

Huang W N，Lin Z A. Chin. J. Chromatogr.（黄维妮，林子俺. 色谱），2021，39（1）：1-3.

Zhang Z H，Liu Y F，Peng Y，Wang J，Li Q Z，Zhai C P，Xiao Q，Zheng J G. J. Instrum. Anal.（张子豪，刘莹峰，彭莹，王晶，李全忠，翟翠萍，肖前，郑建国. 分析测试学报），2022，41（10）：1536-1541.

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Determination of 37 Liquid Crystal Monomers in Indoor Dust by Using QuEChERS Coupled with Gas Chromatography- Tandem Mass Spectrometry

Determination of 16 Hydroxy Polycyclic Aromatic Hydrocarbons in Human Urine by Liquid-Liquid Extraction/Gas Chromatography- Tandem Mass Spectrometry

Related Author

HUO Wei-jiang

SHI Zhi-xiong

LI Hui

QIU Tian

LU Yi-fu

FU Hui

QIAN Jian-kun

BAO Shan

Related Institution

School of Public Health，Capital Medical University

China CDC Key Laboratory of Environment and Population Health，National Institute of Environmental Health，Chinese Center for Disease Control and Prevention

School of Public Health，China Medical University

Center for Global Health，School of Public Health，Nanjing Medical University

深圳市检验检疫科学研究院

Address：100 Xianlie Middle Road, Guangzhou Postal code：510070
Tel：020-87684776,37656606 Fax：020-87684776 Email：fxcsxb@china.com
Technical support is provided by Beijing Founder electronics co., LTD 粤ICP备12017312号-3 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰