Determination of 8 Phthalate Esters in Liquid Cosmetics Using Solid-phase Microextraction/Gas Chromatography-Mass Spectrometry
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Determination of 8 Phthalate Esters in Liquid Cosmetics Using Solid-phase Microextraction/Gas Chromatography-Mass Spectrometry
Vol. 31, Issue 3, Pages: 317-321(2012)
作者机构:
1. 北京化工大学理学院化学系
2. 中国计量科学研究院化学计量与分析科学研究所
3. 云南省计量测试技术研究院
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Determination of 8 Phthalate Esters in Liquid Cosmetics Using Solid-phase Microextraction/Gas Chromatography-Mass Spectrometry. [J]. 31(3):317-321(2012)
DOI:
Determination of 8 Phthalate Esters in Liquid Cosmetics Using Solid-phase Microextraction/Gas Chromatography-Mass Spectrometry. [J]. 31(3):317-321(2012)DOI:
Determination of 8 Phthalate Esters in Liquid Cosmetics Using Solid-phase Microextraction/Gas Chromatography-Mass Spectrometry
A method based on solid-phase microextraction(SPME) technique followed by gas chromatography with mass spectrometry detector(GC-MS) was developed for the determination of 8 phthalic acid esters(PAEs) in liquid cosmetics.The parameters affecting the partitions of analytes such as fiber coating,extraction temperature,stirring speed and salt concentration were optimized.The final SPME method employed a 65 μm polydimethylsiloxane(PDMS)/divinylbenzene(DVB) coating fiber and the saturated sodium chloride solution at 90 ℃ under stir for 60 min,then the fiber was introduced into the GC injector port and the extract was desorbed at 250 ℃ for 4 min.The detection limits for the other 7 PAEs except for DPhP ranged from 0.7 μg?kg-1 to 13.6 μg?kg-1,and the recoveries for spiked samples were between 83% and 97% with RSDs(n=5)of 2.5%-10.0% .For its weak adsorption to fiber coating,the detection limit for DPhP was 75 μg?kg-1 ,and the recovery was 70% with RSD(n=5) of 13.9%.The method was applied in the determination of 8 PAEs in liquid samples with satisfactory results.
Determination of N-Nitrosamines in Rubber Sealing Material by SPME/GC-MS
Determination of Alkyl Ketene Dimer Sizing Agent in Paper by Gas Chromatography-Mass Spectrometry
Qualitative Analysis of Volatile Components in e-liquids by Liquid-Liquid Extraction-Gas Chromatography-Mass Spectrometry and Automated Deconvolution-Kováts Retention Index Method
Polydopamine Modified Titanium Dioxide Nano/Submicro Particles Coating for Solid Phase Microextraction of Phthalic Acid Esters
Determination of Acrylonitrile in Cosmetics by GC-MS Method
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