Differential Pulse Stripping Voltammetry Determination of Cadmium in Water Using Graphene Sheets-Au Composite Nano-particles Modified Screen-printed Carbon Electrodes
|更新时间:
|
Differential Pulse Stripping Voltammetry Determination of Cadmium in Water Using Graphene Sheets-Au Composite Nano-particles Modified Screen-printed Carbon Electrodes
Vol. 30, Issue 11, Pages: 1257-1261(2011)
作者机构:
1. 怀化学院化学与化学工程系
2. 怀化学院民族药用植物资源研究与利用湖南省重点实验室
3. 武汉市化学工业研究所有限责任公司
作者简介:
基金信息:
DOI:
CLC:
扫 描 看 全 文
Differential Pulse Stripping Voltammetry Determination of Cadmium in Water Using Graphene Sheets-Au Composite Nano-particles Modified Screen-printed Carbon Electrodes. [J]. 30(11):1257-1261(2011)
DOI:
Differential Pulse Stripping Voltammetry Determination of Cadmium in Water Using Graphene Sheets-Au Composite Nano-particles Modified Screen-printed Carbon Electrodes. [J]. 30(11):1257-1261(2011)DOI:
Differential Pulse Stripping Voltammetry Determination of Cadmium in Water Using Graphene Sheets-Au Composite Nano-particles Modified Screen-printed Carbon Electrodes
An electrochemical sensor based on graphene sheets(GS) and gold nano-particles(Au) composite nano-particles modified screen-printed carbon electrodes(SPCEs) was fabricated(SPCEs│GS/Au),and an electrochemical method was developed for the determination of trace cadmium(Cd) in water by differential pulse stripping voltammetric(DPSV)method.Au preparation and the construction processes of SPCEs│GS/Au electrode were characterized by scanning electron micrography(SEM),and the electrochemical properties of Cd2+ were investigated.Under the optimum conditions,a good linear relationship was obtained between peak current and Cd2+ concentration in the range of 2.5×10-7-2.5×10-5 g/L(r2=0.998 0) with a detection limit(3σ) of 1.8×10-7 g/L.The method was applied in the determination of Cd2+ concentration in real water samples with recoveries of 96%-107%.The analytical results were consistent with those of the graphite furnace atomic absorption spectrometric(GF-AAS) method.The SPCEs│GS/Au electrode showed a high response current and an enrichment ability due to the modification of composite nano-particles.Therefore,the electrode was suitable for the determination of Cd2+ in water with advantages of disposable design,little sample consumption and simple operation.
Preparation of Graphitic Carbon Nitride and Its Application in Determination of Cadmium
Separation and Preconcentration of Trace Cadmium(Ⅱ) in Water with Aminopropyl Silatrane Immobilized on Mesoporous Silica
Determination of Lead and Cadmium in Rice by Flame Atomic Absorption Spectroscopy after Separation and Preconcentration Using Crosslinked β-Cyclodextrin Modified with TETA
Direct Detection of Cadmium in Aqueous Solution Using Microwave Plasma Torch Coupled with Quadrupole Mass Spectrometry