An automated online gel chromatography/gas chromatography-mass spectrometry(GPC/GC-MS) method was established for the determination of 11 phenoxy acid herbicide residues in fruits.The sample was extracted with acetone-hexane and derivatived with butanol sulfuric acid,then the extract was purified by Florisil solid phase extraction column and analyzed by automated online GPC/GC-MS under selected ion monitoring(SIM) mode.The results indicated that the calibration curves of 11 pesticides were linear in the range of 0.01-1.0 mg/L ,with correlation coefficients of 0.998 7-0.999 9.The average recoveries of 11 phenoxy acid herbicide in fruits at spiked levels of 0.02-0.10 mg/kg ranged from 66%to 112% with relative standard deviations(RSDs) of 3.4%-11.5%.The method has high sensitivity for 11 phenoxy acid herbicides with quantitation limits of 7-10 μg/kg.The method was simple,rapid,sensitive and effective,and could meet the requirement for the simultanous determination of 11 pesticide residues in fruits.
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Pesticide Safety Evaluation Research Center,Institute for Agro-food Standards and Testing Technology,Shanghai Academy of Agricultural Sciences
Shanghai Agriculture Technical Extension Service Center
Panjin Center for Inspection and Testing
Wuhai Inspection and Testing Center
NHC Key Laboratory of Food Safety Risk Assessment, China National Center for Food Safety Risk Assessment