Determination of Residues of Thiacloprid,Flubendiamide and Their Metabolites in Paddy Soil and Water by Ultra Performance Liquid Chromatography
|更新时间:
|
Determination of Residues of Thiacloprid,Flubendiamide and Their Metabolites in Paddy Soil and Water by Ultra Performance Liquid Chromatography
Vol. 32, Issue 1, Pages: 138-142(2013)
作者机构:
1. 南京信息工程大学环境科学与工程学院
2. 环境保护部南京环境科学研究所国家环境保护农药环境评价与污染控制重点实验室
作者简介:
基金信息:
DOI:
CLC:
扫 描 看 全 文
Determination of Residues of Thiacloprid,Flubendiamide and Their Metabolites in Paddy Soil and Water by Ultra Performance Liquid Chromatography. [J]. 32(1):138-142(2013)
DOI:
Determination of Residues of Thiacloprid,Flubendiamide and Their Metabolites in Paddy Soil and Water by Ultra Performance Liquid Chromatography. [J]. 32(1):138-142(2013)DOI:
Determination of Residues of Thiacloprid,Flubendiamide and Their Metabolites in Paddy Soil and Water by Ultra Performance Liquid Chromatography
An ultra performance liquid chromatographic(UPLC) method was developed for the determination of thiacloprid,flubendiamide and their metabolite residues in paddy soil and water.The paddy water was extracted with ethyl acetate,and the organic phase was concentrated to constant.The paddy soil was extracted with acetone-water and the extract was purified by liquid-liquid distribution.The optimization chromatographic conditions were as the follows:separation column:ACQUITY UPLC HSS T3 chromatographic column(2.1 mm×100 mm,1.8 μm),mobile phase:acetonitrile-water,flow rate:0.3 mL?min-1,column temperature:35 ℃,sample volume:5 μL,detection wavelength:230 nm.Under the optimized conditions,the calibration curves of thiacloprid,flubendiamide and their metabolite residues showed good linearities in the range of 0.01-10.00 mg?L-1 with correlation coefficients of 1.000,1.000,0.999 9,respectively.The instrumental detection limits of three compounds were in the range of 0.001-0.002 mg?L-1,and their method detection limits were 0.000 4-0.001 0 mg?L-1 for water sample and 0.002 2-0.003 6 mg?kg-1 for soil sample.The spiked recoveries were in the range of 82%-106% with RSDs(n=5) of 0.81%-3.8%.With the advantages of easy operation,good separation effect,high sensitivity and accuracy,the proposed method was successfully applied in the determination of thiacloprid,flubendiamide and their metabolites in real samples.
Simultaneous Determination of Tolfenpyrad,Flonicamid,Chlorantraniliprole and Flubendiamide in Vegetables and Fruits by High Performance Liquid Chromatography-Tandem Mass Spectrometry
A Method on Residue Analysis of Polyoxin in Paddy Soil and Water
Residue Determination of Niclosamide-olamine in Twenty Two Kinds of Agricultural Products by UPLC-MS/MS
Simultaneous Determination of Clenbuterol,Chloramphenicol and Diethylstilbestrol in Bovine Milk by Isotope Dilution Ultra Performance Liquid Chromatography-Tandem Mass Spectrometry
Determination of Organochlorine Pesticide Residues in Chinese Herbal Tea Granule by Accelerated Solvent Extraction Combined with Gas Chromatography-Negative Chemical Ionization-Mass Spectrometry
Related Author
No data
Related Institution
上海市农业技术推广服务中心
湖南农业大学生物科学技术学院
湖南农业大学农业环境保护研究所
Key Laboratory of Tropical Fruits and Vegetables Quality and Safety for State Market Regulation;Hainan Institute for Food Control
Tea Research Institute,Chinese Academy of Agricultural Sciences