Preparation of A Sensor Based on Graphene Modified Electrode and Molecularly Imprinted Polymers and Its Determination on Dopamine
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Preparation of A Sensor Based on Graphene Modified Electrode and Molecularly Imprinted Polymers and Its Determination on Dopamine
Vol. 32, Issue 5, Pages: 581-585(2013)
作者机构:
1. 常州大学化学与化工学院
2. 嘉兴学院生物与化学工程学院
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Preparation of A Sensor Based on Graphene Modified Electrode and Molecularly Imprinted Polymers and Its Determination on Dopamine. [J]. 32(5):581-585(2013)
DOI:
Preparation of A Sensor Based on Graphene Modified Electrode and Molecularly Imprinted Polymers and Its Determination on Dopamine. [J]. 32(5):581-585(2013)DOI:
Preparation of A Sensor Based on Graphene Modified Electrode and Molecularly Imprinted Polymers and Its Determination on Dopamine
An electrochemical sensor based on dropped molecular imprinted polymers(MIPs) suspension for dopamine was fabricated.Influences of pH value,concentrations of graphene and MIPs were also optimized.The optimal conditions were as follows:pH value:7.0,concentration of graphene:0.5 g/L,concentration of MIPs:20 g/L.Under the optimal conditions,the prepared sensor showed good selectivity and high sensitivity for dopamine.The DPV peak current is linear to the DA concentration in the range of 2.0×10-7-1.0×10-4 mol/L,with a detection limit(S/N=3) of 6.8×10-8 mol/L.The prepared sensor was successfully applied in the determination of dopamine hydrochloride with recoveries of 98%-105%.