A gas chromatography-mass spectrometric(GC-MS) method was developed for the determination of 1,2-dichloroethane in textiles.The samples were extracted with methanol under ultrasonic assistance.The separation and quantification of 1,2-dichloroethane were achieved on an TG-624 column(30 m×0.32 mm×1.8 μm) using temperature programming.The identification and quantification of 1,2-dichloroethane were performed by GC-MS under full scan and selected ion monitoring scan with the external standard method.The result indicated that the calibration curve showed a good linear relationship between peak area and concentration of 1,2-dichloroethane in the range of 0.05-30 mg/L,with a correlation coefficient of 0.999 3.The limit of detection was 0.50 mg/kg.The average recoveries of 1,2-dichloroethane from 7 typical textile matrices including viscose fiber,polyester,wool,nylon,ramie,polyacrylonitrile fiber and cotton,at three spiked concentration levels of 0.5,1.0,5.0 mg/kg were in the range of 85.2%-101.4% with relative standard deviations(RSDs) of 4.0%-7.4%.With the advantages of low detection limit,good accuracy and high precision,the method could be used for residue surveillance of 1,2-dichloroethane in textile samples.
Determination of Organic Halides in Textiles by Ion Chromatography Method with High Temperature Combustion and Water Vapor Absorption
Determination of Quinoline and Isoquinoline in Textiles by Gas Chromatography-Mass Spectrometry
Simultaneous Determination of Six Kinds of Banned Organophosphorous Flame Retardants in Textiles by Gas Chromatography Tandem Mass Spectrometry Combined with Ultrasonic Extraction
Determination and Confirmation of Five Organotin Compounds in Textiles by Gas Chromatography Tandem Mass Spectrometry
Determination of Kelevan Residue in Textiles by High Performance Liquid Chromatography-Tandem Mass Spectrometry
Related Author
No data
Related Institution
School of Science,China Pharmaceutical University
Nanjing Jinjian Inspection Co.,Ltd
Nanjing Customs Industrial Products Testing Center