Determination of Multi-pesticide Residues in Green Tea by Nano Bamboo Charcoal-dSPE/Ultra High Performance Liquid Chromatography-Tandem Mass Spectrometry
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Determination of Multi-pesticide Residues in Green Tea by Nano Bamboo Charcoal-dSPE/Ultra High Performance Liquid Chromatography-Tandem Mass Spectrometry
Vol. 33, Issue 6, Pages: 642-647(2014)
作者机构:
中国农业科学院茶叶研究所农产品质量安全研究中心
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Determination of Multi-pesticide Residues in Green Tea by Nano Bamboo Charcoal-dSPE/Ultra High Performance Liquid Chromatography-Tandem Mass Spectrometry. [J]. 33(6):642-647(2014)
DOI:
Determination of Multi-pesticide Residues in Green Tea by Nano Bamboo Charcoal-dSPE/Ultra High Performance Liquid Chromatography-Tandem Mass Spectrometry. [J]. 33(6):642-647(2014)DOI:
Determination of Multi-pesticide Residues in Green Tea by Nano Bamboo Charcoal-dSPE/Ultra High Performance Liquid Chromatography-Tandem Mass Spectrometry
Applied in modified QuEChERS(Quick,Easy,Cheap,Effective,Rugged and Safe) method with nano Bamboo Charcoal(NBC) as sorbents for analysis of multi pesticide residues in green tea was developed.Pesticides in tea were extracted with acetonitrile-H2O followed by liquid-liquid partitioning by adding NaCl.The extract was cleaned up using the mixture of NBC-PSA(primary secondary amine)-MgSO4 in dispersive solid-phase step.After separated on an Acquity UPLC TSS-3 C18 column(100 mm×2.1 μm,1.8 μm),the analytes were determined by ultra high performance liquid chromatography-tandem mass spectrometry(UPLC-MS/MS) under multiple reaction monitoring mode(MRM),and quantified by the external standard method.The recoveries for 10 pesticides in tea sample in the fortified concentration range of 0.02-0.50 mg/kg ranged from 72.3% to 116.3% with relative standard deviations(RSD) of 1.4%-13.9%.The limits of quantitation(LOQs) were in the range of 0.02-0.04 mg/kg.The method could meet the requirements for pesticide residue analysis.Furthermore,the method is more commercial than other QuEChERS methods with advantage of low cost of NBC.
关键词
茶叶农药残留纳米竹炭QuEChERS超高效液相色谱-串联质谱(UPLC-MS/MS)
Keywords
teapesticide residuenano Bamboo CharcoalQuEChERSultra performance liquid chromatography-tandem mass spectrometry(UPLC-MS/MS)
Screening of 166 Pesticide Residues in Tea Based on Ultra High Performance Liquid Chromatography-Quadrupole/Electrostatic Field Orbitrap High Resolution Mass Spectrometry
Determination of 35 Pesticide Residues in Green Tea by Gas Chromatography-Triple Quadrupole Mass Spectrometry
Determination of 37 Pesticide Residues in Tea by Gas Chromatography-Tandem Mass Spectrometry Combined with QuEChERS and Prepositive Internal Standard
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Related Institution
Tea Research Institute,Chinese Academy of Agriculture Sciences
College of Chemical Engineering,Zhejiang University of Technology
Rizhao Customs
Technology Center of Qingdao Customs District
Hanzhong Food and Drug Supervision,Inspection and Testing Center,Shaanxi Tea Products Quality Supervision and Inspection Center