The EU Toy Safety Directive which came into force in 2013 has substaintially increased requirements on chemical substances.Restricted migration elements have been increased from 8 to 19 elements,which include trivalent chromium,hexavalent chromium and organotin.Restricted migration amount of N-nitrosamines and restriction of allergenic fragrances have been added.The limited amounts of lead,cadmium,hexavalent chromium,organotin have been decreased to 3.4,0.5,0.005,0.2 mg/kg respectively,and traditional toy testing methods such as inductively coupled plasma-optical emission spectrometry and gas chromatography-mass spectrometry cannot satisfy the testing requirements of hexavalent chromium,organotin,N nitrosamines and fragrances.This paper has briefly described the chemical requirements of TSD and corresponding testing methods,highlighted the technical progress and difficulties of testing methods of hexavalent chromium and organotin.
关键词
玩具欧盟玩具安全指令六价铬有机锡亚硝胺
Keywords
toyEU Toy Safety Directivehexavalent chromiumorganotinN-nitrosamines
Simultaneous Determination of Organophosphorous Flame Retardants in Children’s Toys by High Performance Liquid Chromatography-Mass Spectrometry
Determination of 15 Fragrance Allergens in Toys by Supercritical Carbon Dioxide Fluid Extraction
Determination of Chromium(Ⅲ) and Chromium(Ⅵ) in Children’s Toys Using High Performance Liquid Chromatography-Inductively Coupled Plasma Mass Spectrometry
Preparation of Proficiency Testing Sample for Migration Organic Tin in Toys Paint Coating and Its Application
Determination of 16 Restricted Organotin Compounds in Textile Materials and Their Products by GC-MS