In this paper, a method for rapidly detection the total organic components of PM2.5 by using 13C solid-NMR technique was reported.Reliable information on the organic chemical structure could be obtained without cumbersome sample pre-treatment by this method.Organic components data of PM2.5 from Taiyuan,Xinxiang and Guangzhou were obtained by 13C solid-NMR technique.The result showed that the method was simple,rapid and highly sensitive,and could be applied in the determination of total organic composition of atmospheric aerosol.