Simultaneous Detection of Four Benzotriazole UV Stabilizers in Textiles by Ultra-high Performance Liquid Chromatography-Tandem Mass Spectrometry
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Simultaneous Detection of Four Benzotriazole UV Stabilizers in Textiles by Ultra-high Performance Liquid Chromatography-Tandem Mass Spectrometry
Vol. 35, Issue 4, Pages: 414-419(2016)
作者机构:
1. 福建省纤维检验局
2. 福建省纺织产品检测技术重点实验室
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Simultaneous Detection of Four Benzotriazole UV Stabilizers in Textiles by Ultra-high Performance Liquid Chromatography-Tandem Mass Spectrometry. [J]. 35(4):414-419(2016)
DOI:
Simultaneous Detection of Four Benzotriazole UV Stabilizers in Textiles by Ultra-high Performance Liquid Chromatography-Tandem Mass Spectrometry. [J]. 35(4):414-419(2016)DOI:
Simultaneous Detection of Four Benzotriazole UV Stabilizers in Textiles by Ultra-high Performance Liquid Chromatography-Tandem Mass Spectrometry
A method was developed for the simultaneous determination of four benzotriazole UV stabilizers(BUVSs) including UV-350,UV-320,UV-328 and UV-327 in textiles by ultra high performance liquid chromatography-tandem mass spectrometry(UPLC-MS/MS) combined with ultrasonic extraction(USE).The samples were extracted with acetonitrile saturated with n-hexane under ultrasonic assistance.The separation was performed on an Eclipse Plus C18 column(2.1 mm×50 mm,1.8 μm) using 0.01 mol/L ammonium formate-methanol as mobile phase.Identification and quantification were achieved by UPLC-MS/MS coupled with electrospray ionization(ESI) source in positive ion mode and multiple reactions monitoring(MRM) mode,and the concentration of each analyte was calibrated by the external standard method.The result indicated that the calibration curves of four BUVSs showed good linear relationships between peak areas and certain concentration ranges with correlation coefficients(r2) greater than 0.99.The limits of detection for UV-350,UV-320,UV-328,UV-327 were 0.023,0.024,0.006 3,0.021 mg/kg,respectively.The limits of quantitation were 0.078,0.081,0.021,0.072 mg/kg,respectively.The recoveries at three spiked concentration levels were in the range of 80.0%-102.9% with relative standard deviations(RSDs) of 1.2%-9.9%.The developed method was successfully applied in the determination of BUVSs in textiles.
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超高效液相色谱-串联质谱苯并三唑类紫外稳定剂纺织品超声提取
Keywords
ultra-high performance liquid chromatography-tandem mass spectrometry(UPLC-MS/MS)benzotriazole UV stabilizers(BUVSs)textilesultrasonic extraction(USE)
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Simultaneous Determination of Six Kinds of Banned Organophosphorous Flame Retardants in Textiles by Gas Chromatography Tandem Mass Spectrometry Combined with Ultrasonic Extraction
Determination and Confirmation of Five Organotin Compounds in Textiles by Gas Chromatography Tandem Mass Spectrometry
Determination of Kelevan Residue in Textiles by High Performance Liquid Chromatography-Tandem Mass Spectrometry
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