研究建立了乙烯裂解气中6种主要组分H2,CH4,C2H4,C2H6,C3H6,C3H8的混合气体激光拉曼(Raman)分析法,可将分析时间缩短至约2 min,且无载气、色谱柱等消耗,在加快分析反馈的同时大大降低了仪器维护及使用费用。该方法采用指纹峰浓度曲线,通过筛选计量峰、扣除信号大于3倍信噪比(3 S/N)交叉干扰的修正方式,实现了混合气中6种目标组分的定量分析。在混合气体定量分析中,Raman分析法对H2,C2H4,C3H6,C3H8的定量分析具有较好的测量精度,均小于2%;但对CH4及C2H6的测量精度有待提高,表明所建立的Raman分析法需进一步优化完善。
Rapid determination of CH4,C2H4,C3H6 contents in cracked gas could help grasp the reaction depth in ethylene cracking furnaces and optimize process operations.The most commonly used analytical methods for cracked gas is gas chromatography(GC).Through multiple valves,columns and detectors,full components quantitative information is available by GC.But this takes a long period for analysis,which means 20 min between 2 tests.In contrast,the established laser Raman spectroscopy for 6 main components(H2,CH4,C2H4,C2H6,C3H6 and C3H8) in cracked gas can shorten the analytical time to nearly 2 min.In the meantime,Raman analysis method consumes no cost of carrier gases or chromatographic columns,and sharply cuts the analytical cost.It utilizes concentration curves for quantitative analysis of 6 single component,using 3 times of signal to noise ratio(3 S/N) to correct the cross interferences for quantitative analysis of 6 component in mix gas.In the quantitative analysis of gas mixture,it has a good measurement accuracy in the quantitative analysis of H2,C2H4,C3H6 and C3H8,with relative errors smaller than 2%.But the measurement accuracy on CH4 and C2H6 by Raman analysis method needs to be improved,which means the established Raman analysis method needs further optimization.
激光拉曼气体分析裂解气气态烃
laser Raman spectroscopygas analysiscracked gasgaseous hydrocarbons
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