A gas chromatography-tandem mass spectrometric(GC-MS/MS) method was developed for the determination of 5 carbamate pesticides residues,i.e,metolcarb,isoprocarb,fenobucarb,propoxur and pirimicarb in Oolong tea samples.The sample was extracted with hexane-ethyl acetate mixed solution,and the extract was cleaned up with a QuEChERS kit,including 400 mg PSA/400 mg C18/1 200 mg MgSO4.The mixed targets were separated on a Rxi-5 Sil MS(30 m,0.25 mm×0.25 μm) capillary column,and pesticide residues were identified and quantified by GC-MS/MS.5 carbamate pesticides had good linear relationships in each linear range(5-500 μg/kg for metolcarb and propoxur,1-500 μg/kg for isoprocarb,fenobucarb and pirimicarb),and the correlation coefficients were higher than 0.99.The mean recoveries of metolcarb and propoxur in black Oolong tea at spiked levels of 5,20,100 μg/kg were in the range of 77.5%-95.4%,with RSDs(n=6) of 2.1%-6.1%.The LODs and LOQs for the two targets were 1 μg/kg and 5 μg/kg,respectively.The mean recoveries of isoprocarb,fenobucarb and pirimicarb at spiked levels of 1,20,100 μg/kg were in the range of 79.5%-102.5%with RSDs(n=6) of 2.0%-8.2%.The LODs and LOQs were 0.2 μg/kg and 1 μg/kg,respectively.With the advantages of simple operation,high sensitivity and good reproducibility,this method could meet the requirements for the determination of 5 kinds of carbamate pesticides residues in Oolong tea samples.
关键词
乌龙茶QuEChERS氨基甲酸酯农药气相色谱-串联质谱
Keywords
Oolong-teaQuEChERScarbamate pesticidesgas chromatography-tandem mass spectrometry(GC-MS/MS)
Residue Determination of Niclosamide-olamine in Twenty Two Kinds of Agricultural Products by UPLC-MS/MS
Simultaneous Determination of 16 Coumarins and Vanillins and Their Derivatives in Rice by QuEChERS-Isotope Internal Standard/Ultra-high Performance Liquid Chromatography-Tandem Mass Spectrometry
Screening of 166 Pesticide Residues in Tea Based on Ultra High Performance Liquid Chromatography-Quadrupole/Electrostatic Field Orbitrap High Resolution Mass Spectrometry
Determination of 18 Synthetic Cannabinoids in Chocolate by QuEChERS/High Performance Liquid Chromatography-Quadrupole-Time of Flight Mass Spectrometry
Related Author
No data
Related Institution
College of Horticulture and Landscape,Tianjin Agricultural University
Hainan Provincial Key Laboratory of Quality and Safety for Tropical Fruits and Vegetables;Key Laboratory of Quality and Safety Control for Subtropical Fruit and Vegetable,Ministry of Agriculture and Rural Affairs;Analysis and Test Center,Chinese Academy of Tropical Agricultural Sciences
Tea Research Institute,Chinese Academy of Agricultural Sciences
Key Laboratory of Tropical Fruits and Vegetables Quality and Safety for State Market Regulation;Hainan Institute for Food Control