A rapid and sensitive method was developed for the analysis of 6 polybrominated biphenyl ethers(PBDEs) at trace levels in environmental water samples by gas chromatography-tandem mass spectrometry(GC-MS/MS) with a synthesized zeolite imidazolate framework-8(ZIF-8) as solid phase microextraction coating.The experimental conditions were optimized with single factor tests，and the optimal conditions were as follows：extraction time：50 min，extraction temperature：50 ℃，pH value：70，desorption temperature：280 ℃，desorption time：5 min，and without salt addition.Under the optimized conditions，the calibration curves for 6 PBDEs were linear in the range of 1-1 000 ng/L with limits of detection and limits of quantitation of 008-229 ng/L and 023-732 ng/L,respectively.The intra day and inter day RSDs were in the range of 43%-65% and 69%-93%，respectively.This method was successfully applied in the analysis of PBDEs in 4 environmental water samples(tap water，spring water，pond water and landfill waste water) with recoveries of 816%-109%.