陆怡峰, 李永霞, 张珲姿, 刘鸿, 姚鹤鸣, 郑赛晶, 陈勇. Simultaneous Determination of Heavy Metal Elements in E-cigarette Aerosols by Inductively Coupled Plasma Mass Spectrometry[J]. 2020, 39(6): 729-735.
陆怡峰, 李永霞, 张珲姿, 刘鸿, 姚鹤鸣, 郑赛晶, 陈勇. Simultaneous Determination of Heavy Metal Elements in E-cigarette Aerosols by Inductively Coupled Plasma Mass Spectrometry[J]. 2020, 39(6): 729-735.DOI: doi:10.3969/j.issn.1004-4957.2020.06.005.
A method of inductively coupled plasma mass spectrometry(ICP-MS) with Au solvent trapping was established for the simultaneous determination of 7 kinds of heavy metal elements
i.e.chromium
nickel
arsenic
lead
cadmium
antimony and mercury in e-cigarette aerosols.The trapping conditions for e-cigarette aerosols were optimized.The aerosols were trapped with dilute nitric acid solution(5.0%
by volume) containing 2.0 mg/L Au solution.Two impingers were tandemly connected
in which each contained 25.0 mL trapping solution
and the puffing number was 100.Results showed that
seven elements in e cigarette aerosols were trapped effectively.Under the optimal conditions
the calibration curves were linear in the range of 0.3-80 μg/L for Cr
Ni
As
Pb
Cd
and 0.3-10 μg/L for Sb
Hg
with their correlation coefficients(r2) larger than 0.999.The limits of detection(LODs) for seven elements were in the range of 0.69-1.19 ng/100 puffs
and the limits of quantitation were 2.29-3.97 ng/100 puffs.The recoveries ranged from 96.5% to 103% with relative standard deviations(RSD) of 6.6%-14%10 commercial e-cigarettes were determined by this method and the French Standardization
respectively
and the detection results were consistent.Therefore
this method was accurate
reliable
efficient and low-consumption
which could be used for the detection of heavy metals in e cigarette aerosols.